Metal borohydrides and derivatives–synthesis, structure and properties

M Paskevicius, LH Jepsen, P Schouwink… - Chemical Society …, 2017 - pubs.rsc.org
A wide variety of metal borohydrides, MBH4, have been discovered and characterized
during the past decade, revealing an extremely rich chemistry including fascinating …

[HTML][HTML] Current research progress in magnesium borohydride for hydrogen storage (A review)

Y Lv, Y Wu - Progress in Natural Science: Materials International, 2021 - Elsevier
Hydrogen storage in solid-state materials is believed to be a most promising hydrogen-
storage technology for high efficiency, low risk and low cost. Mg (BH 4) 2 is regarded as one …

A stable 3 V all-solid-state sodium–ion battery based on a closo-borate electrolyte

L Duchêne, RS Kühnel, E Stilp, EC Reyes… - Energy & …, 2017 - pubs.rsc.org
We report on a particularly stable 3 V all-solid-state sodium–ion battery built using a closo-
borate based electrolyte, namely Na2 (B12H12) 0.5 (B10H10) 0.5. Battery performance is …

Metal boranes: Progress and applications

BRS Hansen, M Paskevicius, HW Li, E Akiba… - Coordination Chemistry …, 2016 - Elsevier
Boron and hydrogen have a rich chemistry that has attracted a significant, but mainly
academic, interest during the past century. However, research over the past decades has …

Hydrogen storage in partially exfoliated magnesium diboride multilayers

H Gunda, KG Ray, LE Klebanoff, C Dun, MAT Marple… - Small, 2023 - Wiley Online Library
Metal boride nanostructures have shown significant promise for hydrogen storage
applications. However, the synthesis of nanoscale metal boride particles is challenging …

Fast divalent conduction in MB 12 H 12· 12H 2 O (M= Zn, Mg) complex hydrides: effects of rapid crystal water exchange and application for solid-state electrolytes

K Kisu, A Dorai, S Kim, R Hamada… - Journal of Materials …, 2022 - pubs.rsc.org
This work investigates the divalent conduction of Zn2+ and Mg2+ in hydrated closo-type
complex hydrides MB12H12· nH2O (M= Zn, Mg) and the effects of crystal water exchange in …

Complex and liquid hydrides for energy storage

E Callini, ZÖK Atakli, BC Hauback, S Orimo, C Jensen… - Applied Physics A, 2016 - Springer
The research on complex hydrides for hydrogen storage was initiated by the discovery of Ti
as a hydrogen sorption catalyst in NaAlH 4 by Boris Bogdanovic in 1996. A large number of …

Investigation of Mg(BH4)(NH2)-Based Composite Materials with Enhanced Mg2+ Ionic Conductivity

R Le Ruyet, R Berthelot, E Salager… - The Journal of …, 2019 - ACS Publications
Nowadays, the development of rechargeable Mg batteries remains a challenge, especially
due to the difficulty to find a noncorrosive liquid electrolyte with suitable ionic transport …

Anion Reorientations in the Superionic Conducting Phase of Na2B12H12

N Verdal, TJ Udovic, V Stavila, WS Tang… - The Journal of …, 2014 - ACS Publications
Quasielastic neutron scattering (QENS) methods were used to characterize the
reorientational dynamics of the dodecahydro-closo-dodecaborate (B12H122–) anions in the …

An Improved Method for the Synthesis of M2[B12H12] (M = Na, K) and Their Formation Mechanism

H Han, XR Liu, YM Gao, SS Liang, Y **g… - Inorganic …, 2024 - ACS Publications
Polyhedral boranes have potential applications in medicine and material science due to
their unique structure and stability. However, tedious and low-yield synthetic methods limited …