[HTML][HTML] Non-adiabatic effects in elementary reaction processes at metal surfaces

M Alducin, RD Muiño, JI Juaristi - Progress in Surface Science, 2017 - Elsevier
Great success has been achieved in the modeling of gas-surface elementary processes by
the use of the Born-Oppenheimer approximation. However, in metal surfaces low energy …

Computational approaches to dissociative chemisorption on metals: towards chemical accuracy

GJ Kroes - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
We review the state-of-the-art in the theory of dissociative chemisorption (DC) of small gas
phase molecules on metal surfaces, which is important to modeling heterogeneous catalysis …

Disentangling the role of electrons and phonons in the photoinduced CO desorption and CO oxidation on (O, CO)-Ru (0001)

A Tetenoire, JI Juaristi, M Alducin - Frontiers in Chemistry, 2023 - frontiersin.org
The role played by electronic and phononic excitations in the femtosecond laser induced
desorption and oxidation of CO coadsorbed with O on Ru (0001) is investigated using ab …

Photoinduced CO desorption dominates over oxidation on different O+ CO covered Ru (0001) surfaces

A Tetenoire, JI Juaristi, M Alducin - The Journal of Physical …, 2023 - ACS Publications
The photoinduced desorption and oxidation of CO on Ru (0001) is simulated using ab initio
molecular dynamics with electronic friction that accounts for the nonequilibrated excited …

Why ultrafast photoinduced co desorption dominates over oxidation on ru (0001)

A Tetenoire, C Ehlert, JI Juaristi… - The Journal of …, 2022 - ACS Publications
CO oxidation on Ru (0001) is a long-standing example of a reaction that, being thermally
forbidden in ultrahigh vacuum, can be activated by femtosecond laser pulses. In spite of its …

[HTML][HTML] Absence of spillover of hydrogen adsorbed on small palladium clusters anchored to graphene vacancies

A Granja-DelRío, M Alducin, JI Juaristi, MJ López… - Applied Surface …, 2021 - Elsevier
Experimental evidence exists for the enhancement of the hydrogen storage capacity of
porous carbons when these materials are doped with metal nanoparticles. One of the most …

Mechanism of Ultraviolet-Induced CO Desorption from CO Ice: Role of Vibrational Relaxation Highlighted

S Del Fré, AR Santamaría, D Duflot, R Basalgète… - Physical Review Letters, 2023 - APS
Although UV photon-induced CO ice desorption is clearly observed in many cold regions of
the Universe as well as in the laboratory, the fundamental question of the mechanisms …

Photoinduced desorption dynamics of CO from Pd (111): A neural network approach

A Serrano Jiménez, AP Sánchez Muzas… - Journal of chemical …, 2021 - ACS Publications
Modeling the ultrafast photoinduced dynamics and reactivity of adsorbates on metals
requires including the effect of the laser-excited electrons and, in many cases, also the effect …

Reactive and nonreactive scattering of HCl from Au (111): An ab initio molecular dynamics study

G Füchsel, X Zhou, B Jiang, JI Juaristi… - The Journal of …, 2019 - ACS Publications
The HCl+ Au (111) system has recently become a benchmark for highly activated
dissociative chemisorption, which presumably is strongly affected by electron–hole pair …