Ligand-Field Directed Electronic Effects in Heterogenized Bifunctional Co (II) Molecular Clusters Accomplish Efficient Overall Water Splitting
We demonstrate a hitherto unknown approach of employing cobalt organophosphate D4R
cage-clusters,[(RO) PO3Co (L)] 4 (1–4) and [nBu4N][F@{(RO) PO3Co (L)} 4],(1F–4F), where …
cage-clusters,[(RO) PO3Co (L)] 4 (1–4) and [nBu4N][F@{(RO) PO3Co (L)} 4],(1F–4F), where …
Octanuclear Zinc Clusters in Microporous Organic Polymers: Network‐Enhanced Reductive CO2 Fixation to Formamides at Room Temperature
JY Jang, GM Lee, YK Kim, SM Lee, HJ Kim, G Lee… - Small, 2024 - Wiley Online Library
A building block containing eight zincs and eight iodo groups (8 Zn) is obtained by the Zn
complexation of a salen ligand bearing two additional hydroxy groups. Through the …
complexation of a salen ligand bearing two additional hydroxy groups. Through the …
Exploration of Solid-State vs Solution-State Structure in Contact Ion Pair Systems: Synthesis, Characterization, and Solution-State Dynamics of Zinc Diphenyl …
AJ Straiton, JD Parish, JJ Smith, JP Lowe… - Inorganic …, 2023 - ACS Publications
A family of zinc phosphate complexes supported by nitrogen donor-base ligands have been
synthesized, and their molecular structures were identified in both the solid (X-ray …
synthesized, and their molecular structures were identified in both the solid (X-ray …
Pentanuclear lanthanide mono-organophosphates: synthesis, structure, and magnetism
Research on rare-earth phosphates has recently received substantial interest because of
their unique physical and chemical properties. In recent years, because of their low …
their unique physical and chemical properties. In recent years, because of their low …
Development of a 2D Network of Zinc Organophosphate with an 8-Membered Ring Core Having Corrosion Resistance Properties
A 2D framework, ie, zinc organophosphate [Zn (tmbiph)(solv)] 2 (tmbiphH4= tetramethyl-[1,
1′-biphenyl]-4, 4′-diyl bis (dihydrogen phosphate); solv= 2H2O) with an eight-membered …
1′-biphenyl]-4, 4′-diyl bis (dihydrogen phosphate); solv= 2H2O) with an eight-membered …
Lanthanide organophosphate spiro polymers: synthesis, structure, and magnetocaloric effect in the gadolinium polymer
Spirocyclic lanthanide organophosphate polymers,{[Ln (dipp)(dippH)(CH3OH)(H2O)
2](CH3OH) 2} n [Ln= La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9), Ho …
2](CH3OH) 2} n [Ln= La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9), Ho …
Magnetic anisotropy in octahedral Dy (iii) and Yb (iii) complexes
New organophosphate complexes [Ln (dippH) 3 (dippH2) 3]·(H2O) 6,(Ln= Dy, Yb and Y;
dippH2= 2, 6-diisopropylphenyl phosphate), displaying octahedral coordination geometry …
dippH2= 2, 6-diisopropylphenyl phosphate), displaying octahedral coordination geometry …
Dimensionality alteration and intra-versus inter-SBU void encapsulation in zinc phosphate frameworks
4, 4′-Bipyridine-N-oxide (BIPYMO, 1), a less commonly employed coordination polymer
linker, has been used as a ditopic spacer to bridge double-four-ring (D4R) zinc phosphate …
linker, has been used as a ditopic spacer to bridge double-four-ring (D4R) zinc phosphate …
Elusive double-eight-ring zeolitic secondary building unit
The double-eight-ring (D8R), an elusive secondary building unit of zeolites, has been
stabilized for the first time, both in solution and solid-state. The present study further …
stabilized for the first time, both in solution and solid-state. The present study further …
Solvent-assisted structural conversion involving bimetallic complexes based on the tris (oxalato) ferrate (III) unit with the green→ blue→ red crystal color sequence
Three new complexes forming a dynamic system and given by the following formulae:[Cu2
(bpy) 4Fe (ox) 3] NO3· H2O 1,[Fe (bpy) 3] 2 [Fe (ox) 3] NO3· 10H2O 2 and [Cu (bpy) 3] 2 [Fe …
(bpy) 4Fe (ox) 3] NO3· H2O 1,[Fe (bpy) 3] 2 [Fe (ox) 3] NO3· 10H2O 2 and [Cu (bpy) 3] 2 [Fe …