Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances
J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …
Hydroxide-bridged five-coordinate Dy III single-molecule magnet exhibiting the record thermal relaxation barrier of magnetization among lanthanide-only dimers
A hydroxide-bridged centrosymmetric DyIII dimer with each DyIII being five-coordinated has
been synthesized using bulky hindered phenolate ligands. Magnetic studies revealed that …
been synthesized using bulky hindered phenolate ligands. Magnetic studies revealed that …
Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy 4 clusters
WM Wang, XM Kang, HY Shen, ZL Wu… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Three Dy4 clusters,[Dy4 (tmhd) 8 (L) 2 (CH3OH) 2]· CH3OH (1),[Dy4 (hfac) 8 (L) 2 (DMF) 2]·
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …
Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets
CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …
has expanded dramatically from curiosity driven beginnings to molecules that retain …
Structure and Magnetism of LnIII2 (Ln= Gd, Tb, Dy, and Ho) Assemblies Constructed from a Bis (Hydrazone) Compartmental Ligand: Slow Magnetic Relaxation in the …
The aim of the paper was to synthesize a series of LnIII2 (Ln= Gd, Tb, Dy, and Ho)
complexes that offer a great perspective to construct functional magnetic materials. Here, we …
complexes that offer a great perspective to construct functional magnetic materials. Here, we …
3D Ln III-MOFs: slow magnetic relaxation and highly sensitive luminescence detection of Fe 3+ and ketones
F Zhao, XY Guo, ZP Dong, ZL Liu, YQ Wang - Dalton Transactions, 2018 - pubs.rsc.org
Five new 3D isostructural lanthanide metal organic frameworks (Ln-MOFs),[Ln (HL) 1.5
(H2O)(DMF)]· 2H2O (Ln= GdIII (1), SmIII (2), DyIII (3), EuIII (4) and TbIII (5), H3L= 5-(3′, 5 …
(H2O)(DMF)]· 2H2O (Ln= GdIII (1), SmIII (2), DyIII (3), EuIII (4) and TbIII (5), H3L= 5-(3′, 5 …
SMM behaviour of heterometallic dinuclear Cu II Ln III (Ln= Tb and Dy) complexes derived from N 2 O 3 donor unsymmetrical ligands
Complexes [CuL1](1) and [CuL2](2) of two unsymmetrical N2O3 donor ligands (where H2L1
and H2L2 are N-salicylidene-N′-3-ethoxysalicylidene-1, 3-propanediamine and N …
and H2L2 are N-salicylidene-N′-3-ethoxysalicylidene-1, 3-propanediamine and N …
Effect of bridging ligands on magnetic behavior in dinuclear dysprosium cores supported by polyoxometalates
A family of dinuclear dysprosium cores bridged by different ligands within a
polyoxometalates (POMs) framework,(TBA) 8.5 H1. 5 [(PW11O39) 2Dy2X2 (H2O) 2]· 6H2O …
polyoxometalates (POMs) framework,(TBA) 8.5 H1. 5 [(PW11O39) 2Dy2X2 (H2O) 2]· 6H2O …
Large Energy Barrier and Magnetization Hysteresis at 5 K for a Symmetric {Dy2} Complex with Spherical Tricapped Trigonal Prismatic DyIII Ions
The introduction of the Schiff base ligand N-salicylidene-2-amino-5-chlorobenzoic acid
(sacbH2) in 4f-metal chemistry has afforded a new dinuclear complex,[Dy2 (NO3) 4 (sacbH) …
(sacbH2) in 4f-metal chemistry has afforded a new dinuclear complex,[Dy2 (NO3) 4 (sacbH) …
Selective Coordination of Self-Assembled Hexanuclear [Ni4Ln2] and [Ni2Mn2Ln2] (Ln = DyIII, TbIII, and HoIII) Complexes: Stepwise Synthesis, Structures, and …
The versatility for a unique aggregation of heterometallic 3d–4f and 3d–3d′–4f ions by the
new Schiff base ligand 2-{[(2-hydroxy-3-methoxybenzyl) imino] methyl} phenol (H2L) …
new Schiff base ligand 2-{[(2-hydroxy-3-methoxybenzyl) imino] methyl} phenol (H2L) …