Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

Hydroxide-bridged five-coordinate Dy III single-molecule magnet exhibiting the record thermal relaxation barrier of magnetization among lanthanide-only dimers

J **ong, HY Ding, YS Meng, C Gao, XJ Zhang… - Chemical …, 2017 - pubs.rsc.org
A hydroxide-bridged centrosymmetric DyIII dimer with each DyIII being five-coordinated has
been synthesized using bulky hindered phenolate ligands. Magnetic studies revealed that …

Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy 4 clusters

WM Wang, XM Kang, HY Shen, ZL Wu… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Three Dy4 clusters,[Dy4 (tmhd) 8 (L) 2 (CH3OH) 2]· CH3OH (1),[Dy4 (hfac) 8 (L) 2 (DMF) 2]·
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …

Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets

CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

3D Ln III-MOFs: slow magnetic relaxation and highly sensitive luminescence detection of Fe 3+ and ketones

F Zhao, XY Guo, ZP Dong, ZL Liu, YQ Wang - Dalton Transactions, 2018 - pubs.rsc.org
Five new 3D isostructural lanthanide metal organic frameworks (Ln-MOFs),[Ln (HL) 1.5
(H2O)(DMF)]· 2H2O (Ln= GdIII (1), SmIII (2), DyIII (3), EuIII (4) and TbIII (5), H3L= 5-(3′, 5 …

Structure and magnetism of LnIII2 (Ln= Gd, Tb, Dy, and Ho) assemblies constructed from a bis (hydrazone) compartmental ligand: Slow magnetic relaxation in the …

P Bhattacharya, R Bag, S Satpathi, SK Pati… - Crystal Growth & …, 2023 - ACS Publications
The aim of the paper was to synthesize a series of LnIII2 (Ln= Gd, Tb, Dy, and Ho)
complexes that offer a great perspective to construct functional magnetic materials. Here, we …

Effect of bridging ligands on magnetic behavior in dinuclear dysprosium cores supported by polyoxometalates

Y Huo, YC Chen, SG Wu, JL Liu, JH Jia… - Inorganic …, 2018 - ACS Publications
A family of dinuclear dysprosium cores bridged by different ligands within a
polyoxometalates (POMs) framework,(TBA) 8.5 H1. 5 [(PW11O39) 2Dy2X2 (H2O) 2]· 6H2O …

New Candy-Shaped Hexanuclear CoII2CoIII2Gd2 Aggregate: Synthesis, Structures, and Magnetic Performance for Magnetocaloric Effect and Theoretical …

B Dutta, Z Jagličić, M Fitta, R Herchel… - Crystal Growth & …, 2024 - ACS Publications
The hexanuclear cobalt (II/III)–gadolinium (III) coordination aggregate [CoII2CoIII2Gd2 (L) 2
(μ3-OMe) 2 (Me3CCOO) 8]· H2O (1) has been synthesized and characterized, and structural …

Large Energy Barrier and Magnetization Hysteresis at 5 K for a Symmetric {Dy2} Complex with Spherical Tricapped Trigonal Prismatic DyIII Ions

EC Mazarakioti, J Regier, L Cunha-Silva… - Inorganic …, 2017 - ACS Publications
The introduction of the Schiff base ligand N-salicylidene-2-amino-5-chlorobenzoic acid
(sacbH2) in 4f-metal chemistry has afforded a new dinuclear complex,[Dy2 (NO3) 4 (sacbH) …

SMM behaviour of heterometallic dinuclear Cu II Ln III (Ln= Tb and Dy) complexes derived from N 2 O 3 donor unsymmetrical ligands

S Maity, P Bhunia, K Ichihashi, T Ishida… - New Journal of …, 2020 - pubs.rsc.org
Complexes [CuL1](1) and [CuL2](2) of two unsymmetrical N2O3 donor ligands (where H2L1
and H2L2 are N-salicylidene-N′-3-ethoxysalicylidene-1, 3-propanediamine and N …