Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Dynamic magnetic MOFs

E Coronado, GM Espallargas - Chemical Society Reviews, 2013 - pubs.rsc.org
In this review we combine the use of coordination chemistry with the concepts of molecular
magnetism to design magnetic Metal–Organic Frameworks (MOFs) in which the crystalline …

Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry

JP Sutter, V Béreau, V Jubault, K Bretosh… - Chemical Society …, 2022 - pubs.rsc.org
The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …

Microporous magnets

P Dechambenoit, JR Long - Chemical Society Reviews, 2011 - pubs.rsc.org
Combining porosity and magnetic ordering in a single material presents a significant
challenge since magnetic exchange generally requires short bridges between the spin …

Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Magnetically ordered molecule-based materials

JS Miller - Chemical Society Reviews, 2011 - pubs.rsc.org
Magnets composed of molecular components that provide both electron spins and spin-
coupling pathways can stabilize bulk magnetic ordering. This was first reported for the ionic …

Photomagnetism in cyano-bridged bimetal assemblies

S Ohkoshi, H Tokoro - Accounts of chemical research, 2012 - ACS Publications
The study of photoinduced phase-transition materials has implications for the fields of
inorganic chemistry, solid-state chemistry, and materials science. Cyano-bridged bimetal …

A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from Tc = 26 to 80 K

IR Jeon, B Negru, RP Van Duyne… - Journal of the American …, 2015 - ACS Publications
The incorporation of tetraoxolene radical bridging ligands into a microporous magnetic solid
is demonstrated. Metalation of the redox-active bridging ligand 2, 5-dichloro-3, 6-dihydroxy …

Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework

Y **n, J Wang, M Zychowicz… - Journal of the …, 2019 - ACS Publications
Microporous magnets compose a class of multifunctional molecule-based materials where
desolvation-driven structural transformation leads to the switching of magnetic properties …