The development of molecular materials with novel functionality offers promise for
technological innovation. Switchable molecules that incorporate redox‐active components …

The lack of systematic structural resolution makes it difficult to build specific transition‐metal‐
atom‐doped carbonized polymer dots (TMA‐doped CPDs). Herein, the structure‐activity …

Rare earth elements (REEs) have been widely applied in modern industry and material
science due to their special chemical properties and luminescence properties, but their …

As the key intermediates in metal-catalyzed [2+ 2+ 2] cycloaddition reactions of three
alkynes, main-group and transition-metal metallacycloheptatrienes have been studied for …

Homoleptic tetramethylaluminates Ln (AlMe4) 3 react with KTp t Bu, Me (Tp t Bu, Me= tris (3-t
Bu-5-Me-pyrazolyl) borato) to yield rare-earth-metal methylidene complexes (Tp t Bu, Me) Ln …

The synthesis, electronic structure, and reactivity of a uranium metallacyclopropene were
comprehensively studied. Addition of diphenylacetylene (PhC≡ CPh) to the uranium …

The concept of metalla-aromaticity proposed by Thorn–Hoffmann (Nouv. J. Chim. 1979, 3,
39) has been expanded to organometallic molecules of transition metals that have more …

Comprehensive Summary Metallacyclopentadienes play a vital role in transition‐metal
mediated and catalyzed cycloaddition reactions of alkynes. Though versatile reactions of …

Dicarbanion compounds, namely organo-bi-metallics in which two metal atoms are
separated by all-carbon backbones, are of great importance in organometallic chemistry for …

In contrast to transition metals, rare-earth metal-promoted sp2–sp carbon–carbon coupling
through reductive elimination cannot be realized due to the inaccessibility of two-electron …