Transition metal-catalyzed C–H amination: scope, mechanism, and applications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …
synthetic approach to construct N-functionalized molecules. Over the last few decades …
Transition metal-catalyzed site-and regio-divergent C–H bond functionalization
L **, DS Chung, J Bouffard, S Lee - Chemical Society Reviews, 2017 - pubs.rsc.org
Recent advances in transition metal-catalyzed C–H bond functionalization have profoundly
impacted synthetic strategy. Since organic substrates typically contain several chemically …
impacted synthetic strategy. Since organic substrates typically contain several chemically …
Mechanistic studies on the Rh (III)-mediated amido transfer process leading to robust C–H amination with a new type of amidating reagent
Mechanistic investigations on the Cp* Rh (III)-catalyzed direct C–H amination reaction led us
to reveal the new utility of 1, 4, 2-dioxazol-5-one and its derivatives as highly efficient amino …
to reveal the new utility of 1, 4, 2-dioxazol-5-one and its derivatives as highly efficient amino …
Transition-metal-catalyzed site-selective C7-functionalization of indoles: advancement and future prospects
C7-Decorated indoles are important structural motifs present in a plethora of bioactive and
pharmaceutical compounds. Early stage developments for C7 modifications were realized …
pharmaceutical compounds. Early stage developments for C7 modifications were realized …
Cooperative Effects between Chiral Cpx–Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C−H Amidations of Phosphine Oxides
YS Jang, M Dieckmann, N Cramer - Angewandte Chemie, 2017 - Wiley Online Library
An enantioselective C− H amidation of phosphine oxides by using an iridium (III) catalyst
bearing an atropchiral cyclopentadienyl (Cpx) ligand is reported. A very strong cooperative …
bearing an atropchiral cyclopentadienyl (Cpx) ligand is reported. A very strong cooperative …
Mechanochemical Iridium (III)‐Catalyzed C− H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent‐Free Conditions in a Ball Mill
Mechanochemical conditions have been applied to an iridium (III)‐catalyzed C− H bond
amidation process for the first time. In the absence of solvent, the mechanochemical …
amidation process for the first time. In the absence of solvent, the mechanochemical …
Powerful direct C–H amidation polymerization affords single-fluorophore-based white-light-emitting polysulfonamides by fine-tuning hydrogen bonds
The development of white-light-emitting polymers has been actively pursued because of the
importance of such polymers in various applications, such as lighting sources and displays …
importance of such polymers in various applications, such as lighting sources and displays …
Rh (III)-catalyzed C7-thiolation and selenation of indolines
W **e, B Li, B Wang - The Journal of Organic Chemistry, 2016 - ACS Publications
The rhodium (III)-catalyzed intermolecular C7-thiolation and selenation of indolines with
disulfides and diselenides were developed. This protocol relies on the use of a removable …
disulfides and diselenides were developed. This protocol relies on the use of a removable …
A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides
Ir (III)-catalyzed regioselective direct C-7 amidation of indoles in reaction with organic azides
has been developed. While its efficiency was varied by the choice of N-directing groups, N …
has been developed. While its efficiency was varied by the choice of N-directing groups, N …
Ir(III)-Catalyzed Synthesis of Isoquinoline N-Oxides from Aryloxime and α-Diazocarbonyl Compounds
An efficient Ir (III)-catalyzed C–H activation and annulations of aryloxime with α-
diazocarbonyl compounds has been developed for the synthesis of substituted isoquinoline …
diazocarbonyl compounds has been developed for the synthesis of substituted isoquinoline …