Ligand-promoted palladium-catalyzed aerobic oxidation reactions
Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …
application and extensive research efforts for nearly 60 years. A significant transition …
Fundamentals of green chemistry: efficiency in reaction design
RA Sheldon - Chemical Society Reviews, 2012 - pubs.rsc.org
In this tutorial review, the fundamental concepts underlying the principles of green and
sustainable chemistry-atom and step economy and the E factor-are presented, within the …
sustainable chemistry-atom and step economy and the E factor-are presented, within the …
Transition metal based catalysts in the aerobic oxidation of alcohols
C Parmeggiani, F Cardona - Green Chemistry, 2012 - pubs.rsc.org
The oxidation of alcohols to the corresponding carbonyl compounds is a pivotal reaction in
organic synthesis. However, traditional oxidants are often toxic and release considerable …
organic synthesis. However, traditional oxidants are often toxic and release considerable …
Palladium oxidase catalysis: selective oxidation of organic chemicals by direct dioxygen‐coupled turnover
SS Stahl - Angewandte Chemie International Edition, 2004 - Wiley Online Library
Selective aerobic oxidation of organic molecules is a fundamental and practical challenge in
modern chemistry. Effective solutions to this problem must overcome the intrinsic reactivity …
modern chemistry. Effective solutions to this problem must overcome the intrinsic reactivity …
Green, catalytic oxidations of alcohols
RA Sheldon, IWCE Arends, GJ Ten Brink… - Accounts of Chemical …, 2002 - ACS Publications
Three methods are described, in the context of the guiding principles of green chemistry, for
the catalytic oxidation of alcohols. The first employs a recyclable oligomeric TEMPO catalyst …
the catalytic oxidation of alcohols. The first employs a recyclable oligomeric TEMPO catalyst …
Pd (II)-catalyzed regioselective 2-alkylation of indoles via a norbornene-mediated C–H activation: mechanism and applications
L Jiao, E Herdtweck, T Bach - Journal of the American Chemical …, 2012 - ACS Publications
A palladium-catalyzed direct 2-alkylation reaction of free NH indoles was developed based
on a norbornene-mediated regioselective cascade C–H activation. The detailed reaction …
on a norbornene-mediated regioselective cascade C–H activation. The detailed reaction …
Recent advances in green catalytic oxidations of alcohols in aqueous media
RA Sheldon - Catalysis Today, 2015 - Elsevier
Catalytic oxidations of alcohols, with dioxygen or hydrogen peroxide as the primary oxidant,
in aqueous reaction media are reviewed. Selective alcohol oxidations with hydrogen …
in aqueous reaction media are reviewed. Selective alcohol oxidations with hydrogen …
Transition-metal-free: A highly efficient catalytic aerobic alcohol oxidation process
R Liu, X Liang, C Dong, X Hu - Journal of the American Chemical …, 2004 - ACS Publications
A highly efficient catalytic system without transition metals has been developed for aerobic
alcohol oxidations. Under the optimal reaction conditions, various alcohol substrates were …
alcohol oxidations. Under the optimal reaction conditions, various alcohol substrates were …
Palladium-catalysed oxidation of primary and secondary alcohols
J Muzart - Tetrahedron, 2003 - Elsevier
The transformation of the hydroxy group into the corresponding carbonyl is one of the most
frequently used reactions in organic synthesis. Traditionally, stoichiometric and even over …
frequently used reactions in organic synthesis. Traditionally, stoichiometric and even over …
Recent advances in homogeneous transition metal-catalyzed aerobic alcohol oxidations
MJ Schultz, MS Sigman - Tetrahedron, 2006 - Elsevier
Conclusion The last 10 years has seen a considerable increase of interest in the area of
metal-catalyzed aerobic alcohol oxidations. Of the work presented in this review, Markó's Cu …
metal-catalyzed aerobic alcohol oxidations. Of the work presented in this review, Markó's Cu …