Utilization of Hypervalent Bonds as a Novel Strategy for Manipulating Energy Levels of π‐Conjugated Systems

M Gon, K Tanaka - European Journal of Organic Chemistry, 2024 - Wiley Online Library
The unique optical properties created by the combination of azobenzene‐based π‐
conjugated systems and hypervalent bonds are summarized. The hypervalent bond, a …

Preparation of seven-coordinated hypervalent tin (iv)-fused azobenzene and applications for stimuli-responsive π-conjugated polymer films

M Gon, Y Morisaki, K Tanimura, K Tanaka - Dalton Transactions, 2024 - pubs.rsc.org
Heavy atoms can form highly coordinated states, and their optical properties have attracted
much attention. Recently, we have demonstrated that a reversible coordination-number shift …

Creation of Excitation‐Driven Hypervalent Tin (IV) Compounds For Aggregation‐Induced Emission and Application to Thermoresponsive Luminescent Films Below …

M Gon, K Shibahara, K Tanimura… - Chemistry–An Asian …, 2024 - Wiley Online Library
Although many researchers have devoted their much effort to establish the strategy for
develo** a stimuli‐responsive molecule and tuning of their properties according to the …

A selective fluorescent chemosensor for Zinc (II) in aqueous medium and its bioimaging application

Y Wang, J Huang, T Bi, Y Tian, Q Shen… - Journal of Molecular …, 2025 - Elsevier
The development of sensitive and selective methods for detecting zinc ions holds significant
research importance in both environmental and biological contexts. Fluorescent probe …

Effects of Heavy p‐Block Elements on Photophysical Properties of π‐Conjugated Complexes and Organoelement Compounds

S Ito, M Gon, K Tanaka - European Journal of Inorganic …, 2024 - Wiley Online Library
Abstract π‐Conjugated compounds exhibit remarkable photophysical properties, such as
strong light absorption and emission, and are applicable to organic devices, bioimaging …

Organogermanium (IV) complexes with O, N, O'-tridentate Schiff bases: synthesis, electrochemical transformations, photophysical properties, and anti/prooxidant …

DA Burmistrova, NP Pomortseva, MA Kiskin… - Inorganica Chimica …, 2025 - Elsevier
A series of novel diorganogermanium (IV) complexes of the type [R 2 Ge (L n)](where R is
Et, Ph) with O, N, O'-tridentate redox-active Schiff bases has been synthesized. Compounds …

Easy obtention of tin (II) complexes by using semicarbazones in their hydrochloride forms

VD Schwade, VO Araujo, A Lunardi… - Journal of Molecular …, 2024 - Elsevier
Abstract The 2-benzoylpyridine-semicarbazone and 2-benzoylpyridine-N-4-
phenylsemicarbazone can be prepared in their hydrochloride forms, having good solubility …

Luminescent 8-hydroxyquinoline derived tin (IV) complexes

P Pandey, MG Walawalkar, R Murugavel - Journal of Organometallic …, 2024 - Elsevier
Four different 8-hydroxyquinoline derivative-based tin (IV) complexes [(n Bu) 2 Sn (Cl-Q-
CHO) 2](1),[{(n Bu) 4 Sn 2 (Q-COO) 2} 2](2),[Ph 2 Sn (Cl)(Q-CHO)](3) and [Ph 2 Sn (Cl)(Q …

Luminophores Based on Compounds of Groups 13, 14, and 15 Elements and Their Biomedical Applications

EA Nikitin, EM Mironova, ER Milaeva - Russian Journal of Coordination …, 2024 - Springer
Complexes of various metals have a broad scope of applicability as luminescent materials.
These compounds are used both as components of displays, batteries, and semiconductors …

Complexes R2Sn(IV)L with Tridentate O,N,O'-Donor Schiff Bases: Photophysical Properties and Biological Activity

DA Burmistrova, NP Pomortseva, KD Pashaeva… - Russian Journal of …, 2024 - Springer
New tin (IV) complexes (Ln) SnR2 (R= n-Bu (I, II), t-Bu (III–V), and Ph (VI)) with O, N, O'-
donor Schiff bases are synthesized. The molecular structures of compounds I and IV in the …