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Endohedral fullerenes
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …
possibility to use them as robust containers for other species. Although an IUPAC …
When metal clusters meet carbon cages: endohedral clusterfullerenes
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …
Current status and future developments of endohedral metallofullerenes
X Lu, L Feng, T Akasaka, S Nagase - Chemical Society Reviews, 2012 - pubs.rsc.org
Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …
Endohedral metallofullerenes: a unique host–guest association
In this tutorial review taking X-ray crystallographically characterized compounds as a starting
point a walk is taken through the electronic and structural properties of endohedral …
point a walk is taken through the electronic and structural properties of endohedral …
Structure, Stability, and Cluster-Cage Interactions in Nitride Clusterfullerenes M3N@C2n (M = Sc, Y; 2n = 68−98): a Density Functional Theory Study
Extensive semiempirical calculations of the hexaanions of IPR (isolated pentagon rule) and
non-IPR isomers of C68− C88 and IPR isomers of C90− C98 followed by DFT calculations of …
non-IPR isomers of C68− C88 and IPR isomers of C90− C98 followed by DFT calculations of …
Trimetallic nitride template endohedral metallofullerenes: discovery, structural characterization, reactivity, and applications
Shortly after the discovery of the carbon fullerene allotrope, C60, researchers recognized
that the hollow spheroidal shape could accommodate metal atoms, or clusters, which quickly …
that the hollow spheroidal shape could accommodate metal atoms, or clusters, which quickly …
Chemistry of endohedral metallofullerenes: the role of metals
X Lu, T Akasaka, S Nagase - Chemical Communications, 2011 - pubs.rsc.org
Recent breakthroughs achieved in the chemical functionalization of endohedral
metallofullerenes (EMFs), especially single crystallographic X-ray characterizations of their …
metallofullerenes (EMFs), especially single crystallographic X-ray characterizations of their …
M2@C79N (M = Y, Tb): Isolation and Characterization of Stable Endohedral Metallofullerenes Exhibiting M−M Bonding Interactions inside Aza[80]fullerene Cages
Y2@ C79N and Tb2@ C79N have been prepared by conducting the Krätschmer− Huffman
electric-arc process under 20 Torr of N2 and 280 Torr of He with metal oxide-doped graphite …
electric-arc process under 20 Torr of N2 and 280 Torr of He with metal oxide-doped graphite …
Bonding in endohedral metallofullerenes as studied by quantum theory of atoms in molecules
Metal–cage and intracluster bonding was studied in detail by quantum theory of atoms in
molecules (QTAIM) for the four major classes of endohedral metallofullerenes (EMFs) …
molecules (QTAIM) for the four major classes of endohedral metallofullerenes (EMFs) …
Synthesis and characterization of non-isolated-pentagon-rule actinide endohedral metallofullerenes U@ C 1 (17418)-C76, U@ C 1 (28324)-C80, and Th@ C 1 …
For the first time, actinide endohedral metallofullerenes (EMFs) with non-isolated-pentagon-
rule (non-IPR) carbon cages, U@ C80, Th@ C80, and U@ C76, have been successfully …
rule (non-IPR) carbon cages, U@ C80, Th@ C80, and U@ C76, have been successfully …