Recent progress on exploring µ-oxo bridged binuclear porphyrinoid complexes in catalysis and material science
AB Sorokin - Coordination Chemistry Reviews, 2019 - Elsevier
This review covers recent advances in the preparation, characterization and application of µ-
oxo dimeric complexes with different metals and non-metal and macrocyclic ligands …
oxo dimeric complexes with different metals and non-metal and macrocyclic ligands …
From mononuclear iron phthalocyanines in catalysis to μ-nitrido diiron complexes and beyond
AB Sorokin - Catalysis Today, 2021 - Elsevier
For a long time biomimetic oxidation catalysis was mainly associated with metal porphyrin
complexes. Phthalocyanine complexes, also belonging to large family of macrocyclic …
complexes. Phthalocyanine complexes, also belonging to large family of macrocyclic …
Cyclic metalloporphyrin dimers: Conformational flexibility, applications and future prospects
Over the past few decades, cyclic metalloporphyrin dimers have been significantly exploited
in the fields of molecular motion, switches, recognition, biomimetic chemistry, and …
in the fields of molecular motion, switches, recognition, biomimetic chemistry, and …
Aluminum (III) porphyrin: A unique building block for artificial photosynthetic systems
Despite being the most abundant metal on the Earth, aluminum (III) metal ion centered
porphyrin (AlPor, where Por= Porphyrin) derivatives have received much less attention …
porphyrin (AlPor, where Por= Porphyrin) derivatives have received much less attention …
A charge transfer state induced by strong exciton coupling in a cofacial μ-oxo-bridged porphyrin heterodimer
Photosensitizers with high energy, long lasting charge-transfer states are important
components in systems designed for solar energy conversion by multistep electron transfer …
components in systems designed for solar energy conversion by multistep electron transfer …
Binuclear complexes with single MFM bridge (M: Fe, Mn, and Cu): A critical analysis of the impact of fluoride for isoelectronic hydroxide substitution
Metal complexes containing a binuclear structural motif of the type MXM,(M, metal centers
and X, the bridging group), have emerged as an important area of research owing to the …
and X, the bridging group), have emerged as an important area of research owing to the …
Stable Dication Diradicals of Triply Fused Metallo Chlorin‐Porphyrin Heterodimers: Impact of the Bridge on the Control of Spin Coupling to Reactivity
SJ Shah, YA Pandit, E Garribba… - … –A European Journal, 2023 - Wiley Online Library
We report an unexpected rearrangement, controlled by the nature of the bridge, leading to
the formation of novel, remarkably stable triply fused dinickel (II)/dicopper (II) chlorin …
the formation of novel, remarkably stable triply fused dinickel (II)/dicopper (II) chlorin …
Multiheme proteins: effect of heme–heme interactions
The family of multiheme proteins constitutes one of the fascinating molecular machineries
designed by Nature to execute a large variety of functions. A high level of conservation …
designed by Nature to execute a large variety of functions. A high level of conservation …
A new hexanuclear Fe (III) nanocluster: synthesis, structure, magnetic properties, and efficient activity as a precatalyst in water oxidation
The oxo-bridged hexanuclear iron cluster formulated [FeIII6 (μ4-O) 2 (edteH) 2 (piv) 4 (SCN)
4]· 2MeCN· 2H2O (1)(where edteH= N, N, N′, N′-tetrakis (2-hydroxyethyl) …
4]· 2MeCN· 2H2O (1)(where edteH= N, N, N′, N′-tetrakis (2-hydroxyethyl) …
Cooperativity in Diiron (III) porphyrin Dication Diradical-Catalyzed Oxa-Diels–Alder Reactions: Spectroscopic and Mechanistic Insights
Here, we delineate a maiden example of a diiron (III) dication diradical porphyrin dimer as a
competent catalyst for the oxa-Diels–Alder type reaction of aldehydes with 1, 3-dienes …
competent catalyst for the oxa-Diels–Alder type reaction of aldehydes with 1, 3-dienes …