Structural aspects of fullerene chemistry a journey through fullerene chirality
C Thilgen, F Diederich - Chemical reviews, 2006 - ACS Publications
The discovery of the fullerenes, the first molecular allotropes of carbon, in the gas phase in
19851 and the equally remarkable discovery of their synthesis in macroscopic amounts by …
19851 and the equally remarkable discovery of their synthesis in macroscopic amounts by …
Perfluoroalkylfullerenes
Perfluoroalkylfullerenes | Chemical Reviews ACS ACS Publications C&EN CAS Find my
institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most Read …
institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most Read …
Electrochemical, Spectroscopic, and DFT Study of C60(CF3)n Frontier Orbitals (n = 2−18): The Link between Double Bonds in Pentagons and Reduction …
The frontier orbitals of 22 isolated and characterized C60 (CF3) n derivatives, including
seven reported here for the first time, have been investigated by electronic spectroscopy (n …
seven reported here for the first time, have been investigated by electronic spectroscopy (n …
Synthesis and X-ray or NMR/DFT Structure Elucidation of Twenty-One New Trifluoromethyl Derivatives of Soluble Cage Isomers of C76, C78, C84, and C90
Adding 1% of the metallic elements cerium, lanthanum, and yttrium to graphite rod
electrodes resulted in different amounts of the hollow higher fullerenes (HHFs) C76-D 2 (1) …
electrodes resulted in different amounts of the hollow higher fullerenes (HHFs) C76-D 2 (1) …
Synthesis, Structure, and 19F NMR Spectra of 1,3,7,10,14,17,23,28,31,40-C60(CF3)10
IE Kareev, IV Kuvychko, SF Lebedkin… - Journal of the …, 2005 - ACS Publications
A significant improvement in the selectivity of fullerene trifluoromethylation reactions was
achieved. Reaction of trifluoroiodomethane with [60] fullerene at 460° C and [70] fullerene at …
achieved. Reaction of trifluoroiodomethane with [60] fullerene at 460° C and [70] fullerene at …
Synthesis, Spectroscopic and Electrochemical Characterization, and DFT Study of Seventeen C70(CF3)n Derivatives (n=2, 4, 6, 8, 10, 12)
Abstract Eight new C70 (CF3) n derivatives (n= 2, 6, 10, 12) have been synthesized and
characterized by UV/Vis and 19F NMR spectroscopy, cyclic voltammetry, and quantum …
characterized by UV/Vis and 19F NMR spectroscopy, cyclic voltammetry, and quantum …
Selective Synthesis of a Trifluoromethylated Fullerene and the Crystal Structure of C60(CF3)12
SI Troyanov, A Dimitrov… - Angewandte Chemie …, 2006 - Wiley Online Library
Like fluorofullerenes, perfluoroalkyl fullerenes are potential compounds in the further
derivatization of fullerene and the creation of new materials, including light-harvesting …
derivatization of fullerene and the creation of new materials, including light-harvesting …
Synthesis, Characterization, and Theoretical Study of Stable Isomers of C70(CF3)n (n = 2, 4, 6, 8, 10)
EI Dorozhkin, DV Ignat'eva, NB Tamm… - … A European Journal, 2006 - Wiley Online Library
Reaction of C70 with ten equivalents of silver (i) trifluoroacetate at 320–340° C followed by
fractional sublimation at 420–540° C and HPLC processing led to the isolation of a single …
fractional sublimation at 420–540° C and HPLC processing led to the isolation of a single …
Sc3N@(C80-Ih(7))(CF3)14 and Sc3N@(C80-Ih(7))(CF3)16. Endohedral Metallofullerene Derivatives with Exohedral Addends on Four and Eight Triple-Hexagon …
The compounds Sc3N@(C80-I h (7))(CF3) 14 (1) and Sc3N@(C80-I h (7))(CF3) 16 (2) were
prepared by heating Sc3N@ C80-I h (7) and Ag (CF3CO2) to 350° C in a sealed tube. The …
prepared by heating Sc3N@ C80-I h (7) and Ag (CF3CO2) to 350° C in a sealed tube. The …
Variable-Temperature 19F NMR and Theoretical Study of 1, 9-and 1, 7-C60F (CF3) and C s-and C 1-C60F17 (CF3): Hindered CF3 Rotation and Through-Space J FF …
IE Kareev, GS Quiñones, IV Kuvychko… - Journal of the …, 2005 - ACS Publications
Milligram amounts of the new compounds 1, 9-and 1, 7-C60F (CF3)(ca. 85: 15 mixture of
isomers) and C60F3 (CF3) were isolated from a high-temperature C60/K2PtF6 reaction …
isomers) and C60F3 (CF3) were isolated from a high-temperature C60/K2PtF6 reaction …