Rational design of stable functional metal–organic frameworks

Z Chen, KO Kirlikovali, L Shi, OK Farha - Materials horizons, 2023 - pubs.rsc.org
Functional porous metal–organic frameworks (MOFs) have been explored for a number of
potential applications in catalysis, chemical sensing, water capture, gas storage, and …

The state of the field: from inception to commercialization of metal–organic frameworks

Z Chen, MC Wasson, RJ Drout, L Robison… - Faraday …, 2021 - pubs.rsc.org
As chemists and materials scientists, it is our duty to synthesize and utilize materials for a
multitude of applications that promote the development of society and the well-being of its …

Enhanced adsorption capacity of ZIF-8 for chemical warfare agent simulants caused by its morphology and surface charge

S Oh, S Lee, G Lee, M Oh - Scientific reports, 2023 - nature.com
The effective separation of toxic chemicals, including chemical warfare agents (CWAs), from
the environment via adsorption is of great importance because such chemicals pose a …

High throughput methods in the synthesis, characterization, and optimization of porous materials

IG Clayson, D Hewitt, M Hutereau, T Pope… - Advanced …, 2020 - Wiley Online Library
Porous materials are widely employed in a large range of applications, in particular, for
storage, separation, and catalysis of fine chemicals. Synthesis, characterization, and pre …

Degradation of G-type nerve agent simulant with phase-inverted spherical polymeric-MOF catalysts

K Kiaei, MT Nord, NC Chiu… - ACS Applied Materials & …, 2022 - ACS Publications
For the neutralization of chemical warfare agents (CWAs), the generation of an effective
catalyst that can be handled safely and applied in personal protective equipment is required …

Mechanism and kinetics-guided discovery of nanometal scissors to cut phosphoester bonds

QZ Li, H Fan, Z Wang, JJ Zheng, K Fan, X Yan… - ACS …, 2022 - ACS Publications
Nanomaterials (NMs) that catalytically cut phosphoester bonds are of interest in pure
chemistry and importance in develo** frontier technologies toward gene editing, disease …

Reactive porous polymers for detoxification of a chemical warfare agent simulant

D Jung, P Das, A Atilgan, P Li, JT Hupp… - Chemistry of …, 2020 - ACS Publications
While polymers of intrinsic microporosity (PIMs) possess appealing features such as high
surface area, good solubility, and tailorable functional groups on the polymer backbone …

High-throughput experimentation, theoretical modeling, and human intuition: lessons learned in metal–organic-framework-supported catalyst design

KE McCullough, DS King, SP Chheda… - ACS Central …, 2023 - ACS Publications
We have screened an array of 23 metals deposited onto the metal–organic framework
(MOF) NU-1000 for propyne dimerization to hexadienes. By a first-of-its-kind study utilizing …

Realizing the data-driven, computational discovery of metal-organic framework catalysts

AS Rosen, JM Notestein, RQ Snurr - Current Opinion in Chemical …, 2022 - Elsevier
Highlights•Big data approaches are needed to efficiently explore MOF catalyst space.•High-
throughput protocols have been developed to screen large MOF datasets.•Machine learning …

Defect level and particle size effects on the hydrolysis of a chemical warfare agent simulant by UiO-66

B Gibbons, EC Bartlett, M Cai, X Yang… - Inorganic …, 2021 - ACS Publications
Defect engineering in metal–organic frameworks (MOFs) has recently become an area of
significant research due to the possibility of enhancing material properties such as internal …