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Molecular-scale electronics: from concept to function
Creating functional electrical circuits using individual or ensemble molecules, often termed
as “molecular-scale electronics”, not only meets the increasing technical demands of the …
as “molecular-scale electronics”, not only meets the increasing technical demands of the …
Carbon-atom wires: 1-D systems with tunable properties
This review provides a discussion of the current state of research on linear carbon structures
and related materials based on sp-hybridization of carbon atoms (polyynes and cumulenes) …
and related materials based on sp-hybridization of carbon atoms (polyynes and cumulenes) …
A review of functional linear carbon chains (oligoynes, polyynes, cumulenes) and their applications as molecular wires in molecular electronics and optoelectronics
MR Bryce - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Linear, sp-hybridised, 1-dimensional (1D) all-carbon wires are conceptually the simplest π-
conjugated organic molecules. Their fundamental experimental and theoretical properties …
conjugated organic molecules. Their fundamental experimental and theoretical properties …
Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …
with potential application in various domains of science. The key factors responsible for the …
Polyyne rotaxanes: stabilization by encapsulation
LD Movsisyan, M Franz, F Hampel… - Journal of the …, 2016 - ACS Publications
Active metal template Glaser coupling has been used to synthesize a series of rotaxanes
consisting of a polyyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded …
consisting of a polyyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded …
Promising anchoring groups for single-molecule conductance measurements
The understanding of the charge transport through single molecule junctions is a
prerequisite for the design and building of electronic circuits based on single molecule …
prerequisite for the design and building of electronic circuits based on single molecule …
Phenol is a pH-activated linker to gold: a single molecule conductance study
Single molecule conductance measurements typically rely on functional linker groups to
anchor the molecule to the conductive electrodes through a donor–acceptor or covalent …
anchor the molecule to the conductive electrodes through a donor–acceptor or covalent …
Reverse bond-length alternation in cumulenes: candidates for increasing electronic transmission with length
Single-molecule conductance generally decays exponentially with the length of the
molecule when the transport mechanism is a coherent tunneling process. However, it was …
molecule when the transport mechanism is a coherent tunneling process. However, it was …
Solvent dependence of the single molecule conductance of oligoyne-based molecular wires
DC Milan, OA Al-Owaedi, MC Oerthel… - The Journal of …, 2016 - ACS Publications
The conductance and the decay of conductance as a function of molecular length within a
homologous series of oligoynes, Me3Si(C C) n SiMe3 (n= 2, 3, 4, or 5), is shown to …
homologous series of oligoynes, Me3Si(C C) n SiMe3 (n= 2, 3, 4, or 5), is shown to …
Length-Dependent Conduction of Polyynes: Searching for the Limit of the Tunneling Regime
Rigid, conjugated molecules are excellent candidates as molecular wires since they can
achieve full extension between electrodes while maintaining conjugation. Molecular design …
achieve full extension between electrodes while maintaining conjugation. Molecular design …