Molecular-scale electronics: from concept to function

D **ang, X Wang, C Jia, T Lee, X Guo - Chemical reviews, 2016 - ACS Publications
Creating functional electrical circuits using individual or ensemble molecules, often termed
as “molecular-scale electronics”, not only meets the increasing technical demands of the …

Carbon-atom wires: 1-D systems with tunable properties

CS Casari, M Tommasini, RR Tykwinski, A Milani - Nanoscale, 2016 - pubs.rsc.org
This review provides a discussion of the current state of research on linear carbon structures
and related materials based on sp-hybridization of carbon atoms (polyynes and cumulenes) …

A review of functional linear carbon chains (oligoynes, polyynes, cumulenes) and their applications as molecular wires in molecular electronics and optoelectronics

MR Bryce - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Linear, sp-hybridised, 1-dimensional (1D) all-carbon wires are conceptually the simplest π-
conjugated organic molecules. Their fundamental experimental and theoretical properties …

Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications

A Haque, RA Al-Balushi, IJ Al-Busaidi, MS Khan… - Chemical …, 2018 - ACS Publications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

Polyyne rotaxanes: stabilization by encapsulation

LD Movsisyan, M Franz, F Hampel… - Journal of the …, 2016 - ACS Publications
Active metal template Glaser coupling has been used to synthesize a series of rotaxanes
consisting of a polyyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded …

Promising anchoring groups for single-molecule conductance measurements

V Kaliginedi, AV Rudnev, P Moreno-García… - Physical Chemistry …, 2014 - pubs.rsc.org
The understanding of the charge transport through single molecule junctions is a
prerequisite for the design and building of electronic circuits based on single molecule …

Phenol is a pH-activated linker to gold: a single molecule conductance study

B Lawson, HE Skipper, M Kamenetska - Nanoscale, 2024 - pubs.rsc.org
Single molecule conductance measurements typically rely on functional linker groups to
anchor the molecule to the conductive electrodes through a donor–acceptor or covalent …

Reverse bond-length alternation in cumulenes: candidates for increasing electronic transmission with length

MH Garner, W Bro-Jørgensen… - The Journal of …, 2018 - ACS Publications
Single-molecule conductance generally decays exponentially with the length of the
molecule when the transport mechanism is a coherent tunneling process. However, it was …

Solvent dependence of the single molecule conductance of oligoyne-based molecular wires

DC Milan, OA Al-Owaedi, MC Oerthel… - The Journal of …, 2016 - ACS Publications
The conductance and the decay of conductance as a function of molecular length within a
homologous series of oligoynes, Me3Si(C C) n SiMe3 (n= 2, 3, 4, or 5), is shown to …

Length-Dependent Conduction of Polyynes: Searching for the Limit of the Tunneling Regime

Y Gao, E Leary, L Palomino-Ruiz… - Journal of the …, 2025 - ACS Publications
Rigid, conjugated molecules are excellent candidates as molecular wires since they can
achieve full extension between electrodes while maintaining conjugation. Molecular design …