The transition metal-catalysed hydroboration reaction
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …
organic molecules was initially realised several decades ago. Although this area of …
Rare‐earth metal‐catalyzed hydroboration of unsaturated compounds
K Nie, Y Han, C Wang, X Cheng - Applied Organometallic …, 2022 - Wiley Online Library
The reduction of unsaturated compounds is one of the most widely applied transformations
in organic synthesis. Aggressive reductants, highly pressurized hydrogen gas, and …
in organic synthesis. Aggressive reductants, highly pressurized hydrogen gas, and …
A uranium (IV) alkyl complex: synthesis and catalytic property in carbonyl hydroboration
X Sun, X Gong, Z **e, C Zhu - Chinese Journal of Chemistry, 2022 - Wiley Online Library
Comprehensive Summary The strong oxophilicity of actinide complexes prevents their
applications in the transformation of oxygen‐containing substrates. Herein, we report the …
applications in the transformation of oxygen‐containing substrates. Herein, we report the …
N^ N vs. N^ E (E= S or Se) coordination behavior of imino-phosphanamidinate chalcogenide ligands towards aluminum alkyls: efficient hydroboration catalysis of …
The synthesis, characterization, and catalytic application of six aluminum alkyl complexes
supported by various imino-phosphanamidinate chalcogenide ligands are described. Six …
supported by various imino-phosphanamidinate chalcogenide ligands are described. Six …
Synthesis and Structure of a Dimeric Yttrium Complex [LSi(BH3)(C5Me4)Y(CH2SiMe3)2]2 (L = PhC(NtBu)2) and Its Catalytic Application for Hydroboration of …
K Lou, F Zu, J Yi, C Cui - Organometallics, 2021 - ACS Publications
Treatment of cyclopentadienyl-amidinate silylene LSi (C5HMe4)(L= PhC (N t Bu) 2, 1) with
BH3· THF yielded the silylene-borane-functionalized tetramethylcyclopentadiene LSi (BH3) …
BH3· THF yielded the silylene-borane-functionalized tetramethylcyclopentadiene LSi (BH3) …
Synthesis and characterization of rare-earth metallate amido complexes bearing the 2-amidate-functionalized indolyl ligand and their application in the hydroboration …
Y Wei, Q Bao, L Song, D Hong, J Gao, S Wang… - Dalton …, 2022 - pubs.rsc.org
The reactions of 2-amidate-functionalized indolyl proligand 2-(2, 6-iPr2C6H3NHCO)
C8H5NH (H2L) with [(Me3Si) 2N] 3RE (μ-Cl) Li (THF) 3 were studied leading to the …
C8H5NH (H2L) with [(Me3Si) 2N] 3RE (μ-Cl) Li (THF) 3 were studied leading to the …
Aluminium alkyl complexes supported by imino-phosphanamide ligand as precursors for catalytic guanylation reactions of carbodiimides
Herein, we report the synthesis, characterisation, and application of three aluminium alkyl
complexes,[κ2-{NHIRP (Ph) NDipp} AlMe2](R= Dipp (2a), Mes (2b); tBu (2c), Dipp= 2, 6 …
complexes,[κ2-{NHIRP (Ph) NDipp} AlMe2](R= Dipp (2a), Mes (2b); tBu (2c), Dipp= 2, 6 …
Unraveling Ultralong Phosphorescence in Ar2PO(H): n(O) → σ*(PC) Transitions in Ar2PO(H) Stabilize Triplet States Better than n(P) → σ*(PC) in Ar3P
Herein, we report the crystallization-induced persistent room-temperature phosphorescence
(CIpRTP) characteristics of simple diarylphosphine oxides 1, 2, and 3. Under ambient …
(CIpRTP) characteristics of simple diarylphosphine oxides 1, 2, and 3. Under ambient …
Synthesis and structural characterization of 2, 2′: 6, 2 ″-Terpyridine zinc Formate: Hydroboration and hydrosilylation of CO2 and carbonyl compounds
A Loo, GF de la Mora, G Parkin - Polyhedron, 2024 - Elsevier
The zinc formate compound (terpy) Zn (O 2 CH) 2 is obtained via the reaction of Zn (O 2 CH)
2 with 2, 2′: 6′, 2 ″-terpyridine (terpy) and has been structurally characterized by X-ray …
2 with 2, 2′: 6′, 2 ″-terpyridine (terpy) and has been structurally characterized by X-ray …
Distannadithiophenes and Their Application towards Hydroboration of Carbonyl Compounds
Synthesis of distannadithiophenes (C6H6S) 2Sn2Ar4) with different aryl substituents is
presented. These air‐stable distannadithiophenes were tested as catalysts for the …
presented. These air‐stable distannadithiophenes were tested as catalysts for the …