Ferrocene-supported compartmental ligands for the assembly of 3d/4f complexes

A Chakraborty, J Acharya, V Chandrasekhar - ACS omega, 2020 - ACS Publications
Site-specific coordination ligands, also known as compartmental ligands, have been used
for the preparation of heterometallic complexes. These ligands, by virtue of possessing …

Syntheses, Structures, and Magnetic Properties of a Family of Heterometallic Heptanuclear [Cu5Ln2] (Ln = Y(III), Lu(III), Dy(III), Ho(III), Er(III), and Yb(III)) Complexes …

V Chandrasekhar, A Dey, S Das, M Rouzières… - Inorganic …, 2013 - ACS Publications
Sequential reaction of the multisite coordination ligand (LH3) with Cu (OAc) 2· H2O, followed
by the addition of a rare-earth (III) nitrate salt in the presence of triethylamine, afforded a …

Magneto-structural variety of new 3d–4f–4 (5) d heterotrimetallic complexes

D Visinescu, MG Alexandru, AM Madalan… - Dalton …, 2015 - pubs.rsc.org
Three families of heterotrimetallic chains (type 1–type 3), with different topologies, have
been obtained by reacting the 3d–4f complexes,[{Cu (L1)} xLn (NO3) 3] with x= 1 or 2 …

In situ hydrolysis of a carbophosphazene ligand leads to one-dimensional lanthanide coordination polymers. Synthesis, structure and dynamic magnetic studies

N Ahmed, PP Sahu, A Chakraborty, JF Gonzalez… - Dalton …, 2024 - pubs.rsc.org
An in situ hydrolysis of the P–Cl bonds of the carbophosphazene [{NC (NMe2)} 2
{NPCl2}](LPCl2) in the presence of hydrated lanthanide (III) nitrates in a dichloromethane …

Hexanuclear, Heterometallic, Ni3Ln3 Complexes Possessing O-Capped Homo- and Heterometallic Structural Subunits: SMM Behavior of the Dysprosium Analogue

J Goura, R Guillaume, E Rivière… - Inorganic …, 2014 - ACS Publications
The reaction of hetero donor chelating mannich base ligand 6, 6′-{(2-(dimethylamino)
ethylazanediyl) bis (methylene)} bis (2-methoxy-4-methylphenol) with Ni (ClO4) 2· 6H2O …

A Tetranuclear Copper (II)/Calcium (II) Complex as Dual Chemosensor for Colorimetric and Fluorescent Detection of Non‐Steroidal Anti‐Inflammatory Drugs

E Macedi, L Giorgi, M Formica, P Rossi… - …, 2023 - Wiley Online Library
Abstract The tetranuclear Cu2+/Ca2+/Ca2+/Cu2+ complex based on Malten ligand has
been investigated as a platform for anion binding. Simple organic carboxylates and non …

Tetranuclear lanthanide (III) complexes in a seesaw geometry: synthesis, structure, and magnetism

J Goura, JPS Walsh, F Tuna… - Inorganic …, 2014 - ACS Publications
The reaction of 2-methoxy-6-(pyridin-2-ylhydrazonomethyl) phenol (LH) with Ln (III)(Ln= Gd,
Tb, Dy, Ho) salts in the presence of an excess of triethylamine afforded [Gd4 (L) 4 (μ4 …

Heterometallic CuII–DyIII Clusters of Different Nuclearities with Slow Magnetic Relaxation

R Modak, Y Sikdar, G Cosquer, S Chatterjee… - Inorganic …, 2016 - ACS Publications
The synthesis, structures, and magnetic properties of two heterometallic CuII–DyIII clusters
are reported. The first structural motif displays a pentanuclear CuII4DyIII core, while the …

Phosphazene-containing ligands and complexes on their base

IA Nikovskii, EM Chistyakov, AS Tupikov - Russian Journal of General …, 2018 - Springer
Recent developments in the synthesis of phosphazene-based ligands (preparation of
polyfunctional coordination ligands such as pyridyloxy-, pyrazolyl-, phenanthroline …

[HTML][HTML] Heterometallic [Ln (hfac) 3Cu (acac) 2] complexes with late 4f ions

L Bellucci, L Giordano, S Carlotto, G Poneti… - Inorganica Chimica …, 2023 - Elsevier
Abstract Heterometallic [Ln (hfac) 3 Cu (acac) 2] complexes (Ln= Eu 1, Dy 2, Er 3) can be
prepared along the f-transition series. X-rays diffraction studies on well-shaped single …