An isolable germylyne radical with a one-coordinate germanium atom
D Wang, C Zhai, Y Chen, Y He, X Chen, S Wang… - Nature Chemistry, 2023 - nature.com
Abstract Carbynes (R–C:°), species that bear a monovalent carbon atom with three non-
bonding valence electrons, are important intermediates and potentially useful in organic …
bonding valence electrons, are important intermediates and potentially useful in organic …
Rational Design of Persistent Phosphorus-Centered Singlet Tetraradicals and Their Use in Small-Molecule Activation
Biradicals are important intermediates in the process of bond formation and breaking. While
main-group-element-centered biradicals have been thoroughly studied, much less is known …
main-group-element-centered biradicals have been thoroughly studied, much less is known …
Group IV Complexes with Sterically Congested N-Aryl-adamantylcarbamidate Ligands
BR Kheirkhah, W Huadsai, P Liebing… - …, 2023 - ACS Publications
Metalation of N-(2, 6-dibenzhydryl-4-tolyl) adamantane-1-carboxamide (1, Ar* N (H)–C (O)–
Ad) with M (NMe2) 4 (M= Ti, Zr, Hf) yields amidate complexes Ar* N= C (Ad)–O–Ti (NMe2) 3 …
Ad) with M (NMe2) 4 (M= Ti, Zr, Hf) yields amidate complexes Ar* N= C (Ad)–O–Ti (NMe2) 3 …
Novel approach to benzo-fused 1, 2-azaphospholene involving a Pd (II)-assisted tandem P–C bond cleavage and P–N bond formation reaction
New bisphosphine o-Ph2PC6H4C (O) N (H) C6H4PPh2-o (1)(Bala-HariPhos) showed a
unique reactivity towards Pd (II) resulting in a 1, 2-azaphospholene complex, involving a …
unique reactivity towards Pd (II) resulting in a 1, 2-azaphospholene complex, involving a …
A four-membered heterocyclic prevented biradical that can be described as a zwitterion or masked N-heterocyclic phosphinidene
Summary Heterocyclobutane-1, 3-diyls bridge the gap between organic and inorganic
chemistry and are known for the majority of group 13–15 elements. The kinetically stabilized …
chemistry and are known for the majority of group 13–15 elements. The kinetically stabilized …
An Air‐Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P4
BG Steller, CA Roller, M Flock… - Chemistry–An Asian …, 2024 - Wiley Online Library
Controlled insertion into a single P‐P bond of white phosphorus (P4) was achieved by
employing a diaryl stabilized stannylene, Ar* 2Sn (Ar*= 2, 6‐bis (benzhydryl)‐4‐iPr‐phenyl) …
employing a diaryl stabilized stannylene, Ar* 2Sn (Ar*= 2, 6‐bis (benzhydryl)‐4‐iPr‐phenyl) …
Synthesis, characterisation and reactivity studies of chiral β-diketiminate-like supported aluminium Lewis acid complexes towards difficult Diels Alder cycloadditions
D Dissanayake, C Forsyth, D Vidović - Dalton Transactions, 2023 - pubs.rsc.org
Synthesis and characterisation of several chiral, oxazoline containing β-diketiminate type
ligand supported-aluminium compounds are reported. Together with 1 equiv. of Na …
ligand supported-aluminium compounds are reported. Together with 1 equiv. of Na …
Sterically shielded primary anilides of the alkaline-earth metals of the type (thf) n Ae (NH-Ar*) 2 (Ae= Mg, Ca, Sr, and Ba; Ar*= bulky aryl)
P Schüler, S Krieck, H Görls, P Liebing… - Dalton …, 2022 - pubs.rsc.org
Metalation of 2, 4, 6-triphenylphenylamine (H2N-C6H2-2, 4, 6-Ph3, 1a) and 4-methyl-2, 6-
bis (diphenylmethyl) aniline (2, 6-bis (diphenylmethyl)-p-toluidine, H2N-C6H2-4-Me-2, 6 …
bis (diphenylmethyl) aniline (2, 6-bis (diphenylmethyl)-p-toluidine, H2N-C6H2-4-Me-2, 6 …
A Distibene with Extremely Long Sb= Sb Distance and Related Heavier Dipnictenes from Salt‐Free Metathesis Reactions
CA Roller, B Doler, BG Steller, R Saf… - European Journal of …, 2024 - Wiley Online Library
Conversions of organoelement diamides, ArDippE (NMe2) 2 (E= Sb, Bi; ArDipp= C6H3‐2, 6‐
Dipp2), with Ph2SnH2 as reducing agent gave access to low‐valent, heavier group 15 …
Dipp2), with Ph2SnH2 as reducing agent gave access to low‐valent, heavier group 15 …
Hyperbulky 1, 1′-dicarbodiimidoferrocene proligand promotes an asymmetric guanidinate coordination in a Zr (IV) complex
OE Palomero, RA Jones - Polyhedron, 2023 - Elsevier
Abstract The reaction of 1, 1′-diazidoferrocene, PMe 3 and 2, 6-di (phenylmethyl)-4-
methylphenylisocyanate (1) yields the novel hyperbulky proligand 1, 1′-(2, 6-di …
methylphenylisocyanate (1) yields the novel hyperbulky proligand 1, 1′-(2, 6-di …