Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities

C Wu, N Corrigan, CH Lim, W Liu, G Miyake… - Chemical …, 2022 - ACS Publications
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …

Light-accelerated depolymerization catalyzed by Eosin Y

V Bellotti, K Parkatzidis, HS Wang… - Polymer …, 2023 - pubs.rsc.org
Retrieving the starting monomers from polymers synthesized by reversible deactivation
radical polymerization has recently emerged as an efficient way to increase the recyclability …

PET-RAFT polymerization: Mechanistic perspectives for future materials

ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …

Inverse miniemulsion photoiniferter polymerization for the synthesis of ultrahigh molecular weight polymers

RA Olson, ME Lott, JB Garrison… - …, 2022 - ACS Publications
We describe the synthesis of ultrahigh molecular weight water-soluble polymers via
photoiniferter polymerization under inverse miniemulsion conditions. The catalyst-free …

The difference between photo-iniferter and conventional RAFT polymerization: high livingness enables the straightforward synthesis of multiblock copolymers

AC Lehnen, JAM Kurki, M Hartlieb - Polymer Chemistry, 2022 - pubs.rsc.org
Photo-iniferter (PI)–RAFT polymerization, the direct activation of chain transfer agents via
light, is a fascinating polymerization technique, as it overcomes some restriction of …

Excitation dependence in photoiniferter polymerization

RW Hughes, ME Lott, JI Bowman… - ACS Macro …, 2022 - ACS Publications
We report on a fundamental feature of photoiniferter polymerizations mediated with
trithiocarbonates and xanthates. The polymerizations were found to be highly dependent on …

Xanthate-supported photo-iniferter (XPI)-RAFT polymerization: facile and rapid access to complex macromolecules

AC Lehnen, J Gurke, AM Bapolisi, M Reifarth… - Chemical …, 2023 - pubs.rsc.org
Xanthate-supported photo-iniferter (XPI)-reversible addition–fragmentation chain-transfer
(RAFT) polymerization is introduced as a fast and versatile photo-polymerization strategy …

Facile design of renewable lignin copolymers by photoinitiated RAFT polymerization as Pickering emulsion stabilizers

J Liu, X Shi, L Ma, D Zhang, C Lai, C Wang, M Li… - Green …, 2023 - pubs.rsc.org
As the richest aromatic renewable resource, lignin has attracted significant attention for
fabricating various materials. However, due to lignin's structural complexity, an effective and …

Silver sulfide nanocrystals as a biocompatible and full-spectrum photocatalyst for efficient light-driven polymerization under aqueous and ambient conditions

C Yu, J Song, TI Kim, Y Lee, Y Kwon, J Kim, J Park… - ACS …, 2022 - ACS Publications
Owing to current global environmental concerns, polymers must be prepared under eco-
friendly reaction conditions based on sustainable chemistry. In this context, highly efficient …