Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications

SA Younis, EE Kwon, M Qasim, KH Kim, T Kim… - Progress in Energy and …, 2020 - Elsevier
Progress in the design, synthesis, and modification of metal-organic frameworks (MOFs) has
immensely helped expand their applications in a wide variety of research fields. Such …

Engineering the optical response of the titanium-MIL-125 metal–organic framework through ligand functionalization

CH Hendon, D Tiana, M Fontecave… - Journal of the …, 2013 - ACS Publications
Herein we discuss band gap modification of MIL-125, a TiO2/1, 4-benzenedicarboxylate
(bdc) metal–organic framework (MOF). Through a combination of synthesis and …

Metal–organic frameworks as platforms for clean energy

SL Li, Q Xu - Energy & Environmental Science, 2013 - pubs.rsc.org
In order to void environmental pollution and an energy shortage, the application of clean
and renewable energy, such as solar, instead of fossil fuel is foreseen as a prospective …

Force-field prediction of materials properties in metal-organic frameworks

PG Boyd, SM Moosavi, M Witman… - The journal of physical …, 2017 - ACS Publications
In this work, MOF bulk properties are evaluated and compared using several force fields on
several well-studied MOFs, including IRMOF-1 (MOF-5), IRMOF-10, HKUST-1, and UiO-66 …

Maximizing the Photocatalytic Activity of Metal–Organic Frameworks with Aminated-Functionalized Linkers: Substoichiometric Effects in MIL-125-NH2

MB Chambers, X Wang, L Ellezam… - Journal of the …, 2017 - ACS Publications
Despite the promise of utilizing metal–organic frameworks (MOFs) as highly tunable
photocatalytic materials, systematic studies that interrogate the relationship between their …

Quantum-chemical characterization of the properties and reactivities of metal–organic frameworks

SO Odoh, CJ Cramer, DG Truhlar, L Gagliardi - Chemical reviews, 2015 - ACS Publications
The present review is concerned with quantum mechanical electronic structure calculations
on metal− organic frameworks (MOFs) to elucidate their properties and functionalities. There …

Scandium/lithium-functionalized c-IRMOF-10 as a highly efficient and fast-kinetic hydrogen-storage medium: an ab initio DFT and AIMD study

M EL Kassaoui, M Loulidi, A Benyoussef… - ACS Applied Energy …, 2023 - ACS Publications
Isoreticular metal–organic framework-10 (IRMOF-10) beryllium-based nanoporous materials
are receiving great interest as H2-storage media due to the low atomic mass of beryllium …

Computational studies of photocatalysis with metal–organic frameworks

XP Wu, I Choudhuri, DG Truhlar - Energy & Environmental …, 2019 - Wiley Online Library
Metal–organic frameworks (MOFs) as photocatalysts and photocatalyst supports combine
several advantages of homogeneous and heterogeneous catalyses, including stability, post …

On the Electronic and Optical Properties of Metal–Organic Frameworks: Case Study of MIL-125 and MIL-125-NH2

G Capano, F Ambrosio, S Kampouri… - The Journal of …, 2020 - ACS Publications
The photo-active MIL-125 and MIL-125-NH2 metal–organic frameworks (MOFs), despite
having a very similar crystalline structure, exhibit different optical behaviors. Luminescence …