Borates: A rich source for optical materials

M Mutailipu, KR Poeppelmeier, S Pan - Chemical Reviews, 2020 - ACS Publications
The primary goal of this review is to present a clear chemical perspective of borates in order
to stimulate and facilitate the discovery of new borate-based optical materials. These …

Deep-ultraviolet nonlinear optical crystals: concept development and materials discovery

L Kang, Z Lin - Light: Science & Applications, 2022 - nature.com
Deep-ultraviolet (DUV, wavelength λ< 200 nm) nonlinear optical (NLO) crystal is the core
component of frequency conversion to generate DUV laser, which plays an important role in …

Breaking the Inherent Interarrangement of [B3O6] Clusters for Nonlinear Optics with Orbital Hybridization Enhancement

H Qiu, F Li, Z Li, Z Yang, S Pan… - Journal of the American …, 2023 - ACS Publications
The [B3O6] group as a prime functional unit provides borates with intrinsic properties that
are modified by coordination to cations. Inherent [B3O6] cluster structures in borates …

Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2

M Mutailipu, F Li, C **, Z Yang… - Angewandte Chemie …, 2022 - Wiley Online Library
Discovery of new efficient nonlinear optical (NLO) materials with large second‐order
nonlinearity for the short‐wave ultraviolet spectral region (λPM≤ 266 nm, PM= phase …

An excellent deep-ultraviolet birefringent material based on [BO2] infinite chains

F Zhang, X Chen, M Zhang, W **, S Han… - Light: Science & …, 2022 - nature.com
Birefringent materials play indispensable roles in modulating the polarization of light and are
vital in the laser science and technology. Currently, the design of birefringent materials …

Finding the Next Deep-Ultraviolet Nonlinear Optical Material: NH4B4O6F

G Shi, Y Wang, F Zhang, B Zhang, Z Yang… - Journal of the …, 2017 - ACS Publications
Nonlinear optical materials are essential for the development of solid-state lasers.
KBe2BO3F2 (KBBF) is a unique nonlinear optical material for generation of deep-ultraviolet …

Local polarity-induced assembly of second-order nonlinear optical materials

Y Li, J Luo, S Zhao - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Second-order nonlinear optical (NLO) materials, producing coherent light by the
cascaded frequency conversion, are current hot topics in material chemistry and optics, as …

SrB5O7F3 Functionalized with [B5O9F3]6− Chromophores: Accelerating the Rational Design of Deep‐Ultraviolet Nonlinear Optical Materials

M Mutailipu, M Zhang, B Zhang, L Wang… - Angewandte …, 2018 - Wiley Online Library
Fluorooxoborates, benefiting from the large optical band gap, high anisotropy, and ever‐
greater possibility to form non‐centrosymmetric structures activated by the large polarization …

CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

X Wang, Y Wang, B Zhang, F Zhang… - Angewandte …, 2017 - Wiley Online Library
The discovery of new nonlinear optical (NLO) materials for coherent light generation in the
deep‐ultraviolet (DUV, wavelength below 200 nm) region is essential for the development of …

New Functional Groups Design toward High Performance Ultraviolet Nonlinear Optical Materials

H Fan, N Ye, M Luo - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The invention of the laser is a pivotal milestone in the evolution of modern
science and technology. Second-order nonlinear optical (NLO) crystals, which possess the …