Siloxane coordination revisited: Si− O bond character, reactivity and magnificent molecular shapes

F Dankert, C von Hänisch - European Journal of Inorganic …, 2021 - Wiley Online Library
Siloxanes have evolved into a multi‐million dollar business due to their manifold of
commercial and industrial applications. As siloxanes have high hydrophobicity, low basicity …

Recent contributions to the coordination chemistry of beryllium

MR Buchner - Chemistry–A European Journal, 2019 - Wiley Online Library
Given the alleged extreme toxicity of beryllium and its compounds, it is the least investigated
nonradioactive element. However, beryllium exhibits unique properties among the elements …

Beryllium coordination chemistry and its implications on the understanding of metal induced immune responses

MR Buchner - Chemical Communications, 2020 - pubs.rsc.org
The inhalation of beryllium and its compounds can cause the development of chronic
beryllium disease in susceptible individuals. This is caused by a distinct autoimmune …

9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update

JK Buchanan, PG Plieger - Zeitschrift für Naturforschung B, 2020 - degruyter.com
Abstract 9Be solution NMR spectroscopy is a useful tool for the characterisation of beryllium
complexes. An updated comprehensive table of the 9Be NMR chemical shifts of beryllium …

Beryllium halide complexes incorporating neutral or anionic ligands: potential precursors for beryllium chemistry

A Paparo, C Jones - Chemistry–An Asian Journal, 2019 - Wiley Online Library
Reactions of the beryllium dihalide complexes [BeX2 (OEt2) 2](X= Br or I) with N, N, N′,
N′‐tetramethylethylenediamine (TMEDA), a series of diazabutadienes, or bis …

Beryllium‐Mediated Halide and Aryl Transfer onto Silicon

MR Buchner, F Dankert, C Berthold… - … A European Journal, 2023 - Wiley Online Library
The reactivity of hexamethylcyclotrisiloxane (D3) towards BeCl2, BeBr2, BeI2 and [Be3Ph6]
3 was investigated. While BeCl2 only showed unselective reactivity, BeBr2, BeI2 and …

Understanding the Localization of Berylliosis: Interaction of Be2+ with Carbohydrates and Related Biomimetic Ligands

M Müller, MR Buchner - Chemistry–A European Journal, 2019 - Wiley Online Library
The interplay of metal ions with polysaccharides is important for the immune recognition in
the lung. Due to the localization of beryllium associated diseases to the lung, it is likely that …

s-Block chemistry in weakly coordinating solvents

MR Buchner, LR Thomas-Hargreaves - Dalton Transactions, 2021 - pubs.rsc.org
Alkaline earth metal catalysis has been a growing field in recent years. To enhance reactivity
and to understand the metal-substrate interactions in more detail, reactions are increasingly …

Insights into the coordination ability of siloxanes employing partially silicon based crown ethers: A comparative analysis of s-block metal complexes

F Dankert, C von Hänisch - Inorganic Chemistry, 2019 - ACS Publications
Herein we present the synthesis and coordination chemistry of the partially silicon based
crown ether analogues 1, 2, 4, 5-tetrasila-benzo [15] crown-5 (1) and 1, 2, 4, 5-tetrasila [18] …

Synthesis and Derivatives of Beryllium Triflate

W Augustinov, M Müller… - Inorganic …, 2024 - ACS Publications
Various pathways for the synthesis of beryllium triflate were investigated. The reaction of
triflic acid or trimethylsilyl triflate with beryllium metal in liquid ammonia led to the formation …