Next generation multifunctional nano-science of advanced metal complexes with quantum effect and nonlinearity
M Yamashita - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
My research target can be described as “Next Generation Multifunctional Nano-Science of
Advanced Metal Complexes with Quantum Effect and Nonlinearity”. My work encompasses …
Advanced Metal Complexes with Quantum Effect and Nonlinearity”. My work encompasses …
Recent progress on unusual halogen-bridged Pd (III) chain compounds realized by weak ligand field and triple hydrogen bond approaches
The development of new halogen-bridged Pd chain complexes with molecular precision
offers a promising strategy to stabilize Pd (III) ions, which are being considered as future …
offers a promising strategy to stabilize Pd (III) ions, which are being considered as future …
Ni (III) Mott–Hubbard-like state containing high-spin Ni (II) in a semiconductive bromide-bridged Ni-chain compound
M Wakizaka, MR Mian, T Yoshida, T Sato… - Inorganic …, 2022 - ACS Publications
Halogen-bridged linear chain metal complexes (MX-Chains) are fascinating compounds that
have a quasi-one-dimensional (1D) electronic system. In this study, we synthesized the first …
have a quasi-one-dimensional (1D) electronic system. In this study, we synthesized the first …
Multiple-hydrogen-bond approach to uncommon Pd (III) oxidation state: a Pd–Br chain with high conductivity and thermal stability
A Br-bridged Pd chain complex with the Pd ion in an uncommon+ 3 oxidation state,[Pd
(dabdOH) 2Br] Br2 (3), was prepared using a new method involving multiple hydrogen …
(dabdOH) 2Br] Br2 (3), was prepared using a new method involving multiple hydrogen …
Superatomic Stabilization of Dinuclear Platinum (III) through Iodide-Bridged Five-Center Ten-Electron Bonding
One of the goals in synthetic chemistry is to obtain compounds featuring unusual valence
states that are stable under ambient conditions. At present, stabilizing unusual Pt (III) states …
states that are stable under ambient conditions. At present, stabilizing unusual Pt (III) states …
Orthogonal Grade-Separated Nanowiring of Molecular Single Chains
Quasi-one-dimensional (1D) compounds are suitable models to develop future
nanodevices. The critical issue is that most of the several hundred reported 1D compounds …
nanodevices. The critical issue is that most of the several hundred reported 1D compounds …
Elucidating 2D Charge‐Density‐Wave Atomic Structure in an MX–Chain by the 3D‐ΔPair Distribution Function Method
Many solids, particularly low‐dimensional systems, exhibit charge density waves (CDWs). In
one dimension, charge density waves are well understood, but in two dimensions, their …
one dimension, charge density waves are well understood, but in two dimensions, their …
An unusual Pd (III) oxidation state in the Pd–Cl chain complex with high thermal stability and electrical conductivity
The Pd (III) oxidation state is unusual and unstable since it strongly tends to
disproportionate. We synthesized the quasi-one-dimensional (1D) halogen-bridged Pd (III) …
disproportionate. We synthesized the quasi-one-dimensional (1D) halogen-bridged Pd (III) …
Chemical pressure-induced Pt III–I Mott–Hubbard nanowire,[Pt (en) 2 I](Asp-C n) 2· H 2 O (13≤ n), detected via polarized infrared spectroscopy
The electronic states of iodo-bridged platinum nanowire complexes have been studied
using polarized FT-IR spectroscopy. The N–H symmetrical stretching mode was found to be …
using polarized FT-IR spectroscopy. The N–H symmetrical stretching mode was found to be …
Dimensionally Extending from 1D MX–Chain to Ladder and Nanotube Systems: Structural and Electronic Properties
Abstract Molecular one‐dimensional (1D) electron systems have attracted much attention
due to their unique electronic state, physical and chemical properties derived from high …
due to their unique electronic state, physical and chemical properties derived from high …