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Artificial photosynthesis: opportunities and challenges of molecular catalysts
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …
However, the field of molecular catalysis for AP has gradually declined in recent years …
[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …
challenges of the 21st century. Currently, the major part of the global energy supply is …
O–O bond formation in ruthenium-catalyzed water oxidation: single-site nucleophilic attack vs. O–O radical coupling
DW Shaffer, Y ** any type
of water-splitting device. To celebrate its 10 years anniversary, in this Perspective we focus …
of water-splitting device. To celebrate its 10 years anniversary, in this Perspective we focus …
O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts
XP Zhang, HY Wang, H Zheng, W Zhang… - Chinese Journal of …, 2021 - Elsevier
Water oxidation is one of the most important reactions in natural and artificial energy
conversion schemes. In nature, solar energy is converted to chemical energy via water …
conversion schemes. In nature, solar energy is converted to chemical energy via water …
Highly efficient bioinspired molecular Ru water oxidation catalysts with negatively charged backbone ligands
Conspectus The oxygen evolving complex (OEC) of the natural photosynthesis system II
(PSII) oxidizes water to produce oxygen and reducing equivalents (protons and electrons) …
(PSII) oxidizes water to produce oxygen and reducing equivalents (protons and electrons) …
Homogeneous electrocatalytic water oxidation at neutral pH by a robust macrocyclic nickel (II) complex
The development of an earth‐abundant, first‐row water oxidation catalyst that operates at
neutral pH and low overpotential remains a fundamental chemical challenge. Herein, we …
neutral pH and low overpotential remains a fundamental chemical challenge. Herein, we …
Homogeneous Photochemical Water Oxidation by Biuret-Modified Fe-TAML: Evidence of FeV(O) Intermediate
Water splitting, leading to hydrogen and oxygen in a process that mimics natural
photosynthesis, is extremely important for devising a sustainable solar energy conversion …
photosynthesis, is extremely important for devising a sustainable solar energy conversion …
Water oxidation catalysis with nonheme iron complexes under acidic and basic conditions: homogeneous or heterogeneous?
Thermal water oxidation by cerium (IV) ammonium nitrate (CAN) was catalyzed by nonheme
iron complexes, such as Fe (BQEN)(OTf) 2 (1) and Fe (BQCN)(OTf) 2 (2)(BQEN= N, N …
iron complexes, such as Fe (BQEN)(OTf) 2 (1) and Fe (BQCN)(OTf) 2 (2)(BQEN= N, N …
Pt-free tandem molecular photoelectrochemical cells for water splitting driven by visible light
Photoelectrochemical (PEC) cells using molecular catalysts to split water into hydrogen and
oxygen have been investigated intensively during the past years. However, the high-cost of …
oxygen have been investigated intensively during the past years. However, the high-cost of …