Direct conversion of methane to value-added chemicals over heterogeneous catalysts: challenges and prospects

P Schwach, X Pan, X Bao - Chemical reviews, 2017 - ACS Publications
The quest for an efficient process to convert methane efficiently to fuels and high value-
added chemicals such as olefins and aromatics is motivated by their increasing demands …

Heterogeneous catalysis

R Schlögl - Angewandte Chemie International Edition, 2015 - Wiley Online Library
A heterogeneous catalyst is a functional material that continually creates active sites with its
reactants under reaction conditions. These sites change the rates of chemical reactions of …

Dispersed surface Ru ensembles on MgO (111) for catalytic ammonia decomposition

H Fang, S Wu, T Ayvali, J Zheng, J Fellowes… - Nature …, 2023 - nature.com
Ammonia is regarded as an energy vector for hydrogen storage, transport and utilization,
which links to usage of renewable energies. However, efficient catalysts for ammonia …

Spin-related Cu-Co pair to increase electrochemical ammonia generation on high-entropy oxides

S Sun, C Dai, P Zhao, S **, Y Ren, HR Tan… - Nature …, 2024 - nature.com
The electrochemical conversion of nitrate to ammonia is a way to eliminate nitrate pollutant
in water. Cu-Co synergistic effect was found to produce excellent performance in ammonia …

Size‐dependent lattice expansion in nanoparticles: reality or anomaly?

PM Diehm, P Ágoston, K Albe - ChemPhysChem, 2012 - Wiley Online Library
Size‐dependent lattice expansion of nanoparticles is observed for many ionic compounds,
including metal oxides, while lattice contraction prevails for pure metals. However, the …

Syntheses and properties of micro/nanostructured crystallites with high‐energy surfaces

ZY Jiang, Q Kuang, ZX **e… - Advanced Functional …, 2010 - Wiley Online Library
Recently, special attention has been paid to the syntheses of micro/nanostructured
crystallites with high‐energy crystal facets, because high‐energy crystal surfaces usually …

Rapid interchangeable hydrogen, hydride, and proton species at the interface of transition metal atom on oxide surface

S Wu, KY Tseng, R Kato, TS Wu, A Large… - Journal of the …, 2021 - ACS Publications
Hydrogen spillover is the phenomenon where a hydrogen atom, generated from the
dissociative chemisorption of dihydrogen on the surface of a metal species, migrates from …

Reactivity descriptors for ceria in catalysis

M Capdevila-Cortada, G Vilé, D Teschner… - Applied Catalysis B …, 2016 - Elsevier
Ceria has been very successfully employed in oxidation catalysis, whereas its application in
other reactions has been less intensively investigated. The catalytic activity of ceria can be …

Carbon capture by metal oxides: unleashing the potential of the (111) facet

GA Mutch, S Shulda, AJ McCue… - Journal of the …, 2018 - ACS Publications
Solid metal oxides for carbon capture exhibit reduced adsorption capacity following high-
temperature exposure, due to surface area reduction by sintering. Furthermore, only low …

Polarity in oxide nano-objects

C Noguera, J Goniakowski - Chemical reviews, 2013 - ACS Publications
Polar surfaces of compound materials have been the subject of intense activity in the past.
Electrostatic arguments, based on a model of rigid charges, predict that they should have an …