Rational design of thermoresponsive polymers in aqueous solutions: A thermodynamics map

C Zhao, Z Ma, XX Zhu - Progress in Polymer Science, 2019 - Elsevier
Temperature variations may induce changes in solution properties for thermoresponsive
polymers, which have drawn much research attention due to their potential applications in …

Cononsolvency of thermoresponsive polymers: where we are now and where we are going

S Bharadwaj, BJ Niebuur, K Nothdurft, W Richtering… - Soft Matter, 2022 - pubs.rsc.org
Cononsolvency is an intriguing phenomenon where a polymer collapses in a mixture of
good solvents. This cosolvent-induced modulation of the polymer solubility has been …

Smart responsive polymers: Fundamentals and design principles

D Mukherji, CM Marques… - Annual Review of …, 2020 - annualreviews.org
In this review, we summarize recent theoretical and computational developments in the field
of smart responsive materials, together with complementary experimental data. A material is …

Effects of stereochemistry and copolymerization on the LCST of PNIPAm

TE de Oliveira, D Mukherji, K Kremer… - The Journal of chemical …, 2017 - pubs.aip.org
Poly (N-isopropylacrylamide)(PNIPAm) is a smart polymer that presents a lower critical
transition temperature (LCST) of 305 K. Interestingly, this transition point falls within the …

The hydrophobic effect and the role of cosolvents

NFA van der Vegt, D Nayar - The Journal of Physical Chemistry B, 2017 - ACS Publications
Cosolvents modulate aqueous solubility, hydrophobic interactions, and the stability and
function of most proteins in the living cell. Our molecular-level understanding of cosolvent …

Thermoresponsive polymers in non-aqueous solutions

VP Beyer, CR Becer - Polymer Chemistry, 2022 - pubs.rsc.org
Thermoresponsive polymers are gaining increasing interest for numerous applications
especially in the biomedical and nanotechnology fields. The thermoresponsive behaviour of …

Coil–Globule Transition Thermodynamics of Poly(N-isopropylacrylamide)

M Podewitz, Y Wang, PK Quoika… - The Journal of …, 2019 - ACS Publications
Thermosensitive polymers such as poly (N-isopropylacrylamide)(PNIPAM) undergo a phase
transition in aqueous solution from a random-coil structural ensemble to a globule structural …

Numerical modelling of non-ionic microgels: an overview

L Rovigatti, N Gnan, L Tavagnacco, AJ Moreno… - Soft matter, 2019 - pubs.rsc.org
Microgels are complex macromolecules. These colloid-sized polymer networks possess
internal degrees of freedom and, depending on the polymer (s) they are made of, can …

Buckling and Interfacial Deformation of Fluorescent Poly(N-isopropylacrylamide) Microgel Capsules

F Hagemans, F Camerin, N Hazra, J Lammertz, F Dux… - ACS …, 2023 - ACS Publications
Hollow microgels are fascinating model systems at the crossover between polymer vesicles,
emulsions, and colloids as they deform, interpenetrate, and eventually shrink at higher …

Smart polymers for soft materials: from solution processing to organic solids

D Mukherji, K Kremer - Polymers, 2023 - mdpi.com
Polymeric materials are ubiquitous in our everyday life, where they find a broad range of
uses—spanning across common household items to advanced materials for modern …