Transition metal‐catalyzed hydrofunctionalization of methylenecyclopropanes (MCPs) has
presented a considerable challenge due to the difficult manipulation of regioselectivity and …

The radical 1, 4-functionalizations of 1, 3-enynes have emerged as a powerful strategy for
the synthesis of multisubstituted allenes. However, the phosphorus-centered radical-initiated …

Enantioenriched sulfoxides have found ever-increasing applications in marketed drugs or as
candidates in clinical trials. They are also frequently used as key motifs in chiral ligands or …

Hydrophosphination and oxyphosphination are two important topical reactions in order to
prepare organophosphorus derivatives from unsaturated derivatives such as alkenes and …

A general and mild nickel‐catalyzed enantioselective C (sp2)− P cross‐coupling for
synthesizing P‐stereogenic phosphine oxides has been developed. The asymmetric …

The synthesis of P‐stereogenic phosphorus compounds has gained considerable attention
due to their wide applications across many research fields. Among the available strategies …

A mechanism-inspired, reaction mode-controlled enantio-and regioselective anti-
Markovnikov hydrophosphination of unactivated alkynes was accomplished by NiII catalysis …

Transition‐metal‐catalyzed enantioselective P− C cross‐coupling of secondary phosphine
oxides (SPOs) is an attractive method for synthesizing P‐stereogenic phosphorus …

A chiral Brønsted acid‐catalysed asymmetric hydrophosphinylation of 2‐vinylazaarenes by
secondary phosphine oxides is described. A variety of P‐chiral 2‐azaaryl‐ethylphosphine …

Nucleoside analogues have seen significant advancements in treating viral infections and
cancer through ProTide technology, leading to a series of FDA-approved drugs such as …