The Buchwald–Hartwig amination after 25 years
R Dorel, CP Grugel, AM Haydl - … Chemie International Edition, 2019 - Wiley Online Library
The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …
Palladium-catalyzed cross-coupling reactions: a powerful tool for the synthesis of agrochemicals
Pd-catalyzed cross-coupling reactions have become essential tools for the construction of
carbon–carbon and carbon–heteroatom bonds. Over the last three decades, great efforts …
carbon–carbon and carbon–heteroatom bonds. Over the last three decades, great efforts …
Aryl amination using ligand-free Ni (II) salts and photoredox catalysis
EB Corcoran, MT Pirnot, S Lin, SD Dreher, DA DiRocco… - Science, 2016 - science.org
Over the past two decades, there have been major developments in transition metal–
catalyzed aminations of aryl halides to form anilines, a common structure found in drug …
catalyzed aminations of aryl halides to form anilines, a common structure found in drug …
Buchwald-Hartwig reaction: an overview
Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years.
This review underscores selected important recent developments in the catalysis of one of …
This review underscores selected important recent developments in the catalysis of one of …
The Asymmetric Buchwald–Hartwig Amination Reaction
CJ Lu, Q Xu, J Feng, RR Liu - … Chemie International Edition, 2023 - Wiley Online Library
Over the past few decades, the Buchwald–Hartwig reaction has emerged as a powerful tool
for forging C− N bonds, and has been vital to the pharmaceuticals, materials, and catalysis …
for forging C− N bonds, and has been vital to the pharmaceuticals, materials, and catalysis …
Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide
DS Surry, SL Buchwald - Chemical Science, 2011 - pubs.rsc.org
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions
and have been applied in a range of contexts. This perspective attempts to aid the reader in …
and have been applied in a range of contexts. This perspective attempts to aid the reader in …
Reactions of the 21st century: two decades of innovative catalyst design for palladium-catalyzed cross-couplings
PG Gildner, TJ Colacot - Organometallics, 2015 - ACS Publications
A brief account of the major developments of palladium-catalyzed cross-coupling during the
last two decades is highlighted chronologically, with an emphasis on the personal …
last two decades is highlighted chronologically, with an emphasis on the personal …
Biaryl phosphane ligands in palladium‐catalyzed amination
DS Surry, SL Buchwald - Angewandte Chemie International …, 2008 - Wiley Online Library
Palladium‐catalyzed amination reactions of aryl halides have undergone rapid development
in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl …
in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl …
Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides
JF Hartwig - Accounts of chemical research, 2008 - ACS Publications
Many active pharmaceuticals, herbicides, conducting polymers, and components of organic
light-emitting diodes contain arylamines. For many years, this class of compound was …
light-emitting diodes contain arylamines. For many years, this class of compound was …
Selected patented cross-coupling reaction technologies
JP Corbet, G Mignani - Chemical reviews, 2006 - ACS Publications
Many significant products (drugs, materials, optical devices, etc.) commercialized or in the
development phase, possess aromatic carbon-carbon and aromatic carbonnitrogen bonds …
development phase, possess aromatic carbon-carbon and aromatic carbonnitrogen bonds …