Hydroamination: direct addition of amines to alkenes and alkynes

TE Muller, KC Hultzsch, M Yus, F Foubelo… - Chemical …, 2008 - ACS Publications
Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly develo**
fields of research, regarding both fundamental science and solution of applied problems …

Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States 136

WJ Evans - Organometallics, 2016 - ACS Publications
A fundamental aspect of any element is the range of oxidation states accessible for useful
chemistry. This tutorial describes the recent expansion of the number of oxidation states …

Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

M Nishiura, Z Hou - Nature Chemistry, 2010 - nature.com
This Review gives an overview on recent progress in the synthesis and chemistry of rare-
earth metal dialkyl complexes bearing monoanionic ancillary ligands, with an emphasis on …

C H Bond Activation by f‐Block Complexes

PL Arnold, MW McMullon, J Rieb… - Angewandte Chemie …, 2015 - Wiley Online Library
Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

Homoleptic rare-earth metal complexes containing Ln− C σ-bonds

M Zimmermann, R Anwander - Chemical reviews, 2010 - ACS Publications
The past decade has witnessed an enormous growth in the chemistry of σ-bonded rare-
earth metal (Ln) alkyls, particularly due to their relevance for Ziegler-type anionic …

Recent progress in rare-earth metal-catalyzed sp 2 and sp 3 C–H functionalization to construct C–C and C–heteroelement bonds

K Seth - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
C–H functionalization is a fundamentally important organic transformation to access C–C
and C–heteroatom bonds in a common and/or complex molecular set-up during the …

Group 3 metal catalysts for ethylene and α-olefin polymerization

J Gromada, JF Carpentier, A Mortreux - Coordination chemistry reviews, 2004 - Elsevier
This review focuses on the use of group 3 organometallic catalysts for ethylene and α-olefins
polymerization, as well as for functionalization of such poly (α-olefin) chains. It describes the …

β-Diketiminate complexes of the first row transition metals: applications in catalysis

RL Webster - Dalton Transactions, 2017 - pubs.rsc.org
Although β-diketiminate complexes have been widely explored in stoichiometric studies,
their use as catalysts is largely underdeveloped. With growing interest in the catalytic activity …

A quarter-century long story of bis (alkyl) rare-earth (III) complexes

AA Trifonov, DM Lyubov - Coordination Chemistry Reviews, 2017 - Elsevier
A quarter-century long story of bis(alkyl) rare-earth (III) complexes - ScienceDirect Skip to main
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