Shedding light on the role of misfit strain in controlling core–shell nanocrystals

J Zhao, B Chen, F Wang - Advanced Materials, 2020 - Wiley Online Library
Heteroepitaxial modification of nanomaterials has become a powerful means to create novel
functionalities for various applications. One of the most elementary factors in heteroepitaxial …

Building up strain in colloidal metal nanoparticle catalysts

BT Sneed, AP Young, CK Tsung - Nanoscale, 2015 - pubs.rsc.org
The focus on surface lattice strain in nanostructures as a fundamental research topic has
gained momentum in recent years as scientists investigated its significant impact on the …

Reversible loss of core–shell structure for Ni–Au bimetallic nanoparticles during CO2 hydrogenation

X Zhang, S Han, B Zhu, G Zhang, X Li, Y Gao, Z Wu… - Nature Catalysis, 2020 - nature.com
The high catalytic performance of core–shell nanoparticles is usually attributed to their
distinct geometric and electronic structures. Here we reveal a dynamic mechanism that …

Catalytic application of layered double hydroxide-derived catalysts for the conversion of biomass-derived molecules

K Yan, Y Liu, Y Lu, J Chai, L Sun - Catalysis Science & Technology, 2017 - pubs.rsc.org
Layered double hydroxides (LDH) consist of positively-charged metal hydroxide layers and
negatively-charged anions and water in the interstitial layers. Due to the unique properties of …

The exit-wave power-cepstrum transform for scanning nanobeam electron diffraction: robust strain map** at subnanometer resolution and subpicometer precision

E Padgett, ME Holtz, P Cueva, YT Shao, E Langenberg… - Ultramicroscopy, 2020 - Elsevier
Scanning nanobeam electron diffraction (NBED) with fast pixelated detectors is a valuable
technique for rapid, spatially resolved map** of lattice structure over a wide range of …

Interface-mediated Kirkendall effect and nanoscale void migration in bimetallic nanoparticles during interdiffusion

SW Chee, ZM Wong, Z Baraissov, SF Tan… - Nature …, 2019 - nature.com
At elevated temperatures, bimetallic nanomaterials change their morphologies because of
the interdiffusion of atomic species, which also alters their properties. The Kirkendall effect …

Lattice strain measurement of core@ shell electrocatalysts with 4D scanning transmission electron microscopy nanobeam electron diffraction

D Mukherjee, JTL Gamler, SE Skrabalak… - ACS …, 2020 - ACS Publications
Strain engineering enables the direct modification of atomic bonding and is currently an
active area of research aimed at improving electrocatalytic activity. However, directly …

The effect of lattice strain on the catalytic properties of Pd nanocrystals

CH Kuo, LK Lamontagne, CN Brodsky… - …, 2013 - Wiley Online Library
The effect of lattice strain on the catalytic properties of Pd nanoparticles is systematically
studied. Synthetic strategies for the preparation of a series of shape‐controlled Pd …

Nanoscale-phase-separated Pd–Rh boxes synthesized via metal migration: an archetype for studying lattice strain and composition effects in electrocatalysis

BT Sneed, CN Brodsky, CH Kuo… - Journal of the …, 2013 - ACS Publications
Develo** syntheses of more sophisticated nanostructures comprising late transition
metals broadens the tools to rationally design suitable heterogeneous catalysts for chemical …

Preserving surface strain in nanocatalysts via morphology control

C Shi, Z Cheng, A Leonardi, Y Yang, M Engel… - Science …, 2024 - science.org
Engineering strain critically affects the properties of materials and has extensive applications
in semiconductors and quantum systems. However, the deployment of strain-engineered …