Quantum‐mechanical condensed matter simulations with CRYSTAL

R Dovesi, A Erba, R Orlando… - Wiley …, 2018 - Wiley Online Library
The latest release of the Crystal program for solid‐state quantum‐mechanical ab initio
simulations is presented. The program adopts atom‐centered Gaussian‐type functions as a …

Dispersion-corrected mean-field electronic structure methods

S Grimme, A Hansen, JG Brandenburg… - Chemical …, 2016 - ACS Publications
Mean-field electronic structure methods like Hartree–Fock, semilocal density functional
approximations, or semiempirical molecular orbital (MO) theories do not account for long …

CRYSTAL23: A program for computational solid state physics and chemistry

A Erba, JK Desmarais, S Casassa… - Journal of Chemical …, 2022 - ACS Publications
The Crystal program for quantum-mechanical simulations of materials has been bridging the
realm of molecular quantum chemistry to the realm of solid state physics for many years …

Consistent structures and interactions by density functional theory with small atomic orbital basis sets

S Grimme, JG Brandenburg, C Bannwarth… - The Journal of chemical …, 2015 - pubs.aip.org
A density functional theory (DFT) based composite electronic structure approach is
proposed to efficiently compute structures and interaction energies in large chemical …

BSSE‐correction scheme for consistent gaussian basis sets of double‐and triple‐zeta valence with polarization quality for solid‐state calculations

D Vilela Oliveira, J Laun, MF Peintinger… - Journal of …, 2019 - Wiley Online Library
Revised versions of our published pob‐TZVP [Peintinger, MF; Oliveira, DV and Bredow, T.,
J. Comput. Chem., 2013, 34 (6), 451–459.] and unpublished pob‐DZVP basis sets, denoted …

First-principles models for van der Waals interactions in molecules and materials: Concepts, theory, and applications

J Hermann, RA DiStasio Jr, A Tkatchenko - Chemical Reviews, 2017 - ACS Publications
Noncovalent van der Waals (vdW) or dispersion forces are ubiquitous in nature and
influence the structure, stability, dynamics, and function of molecules and materials …

Accurate lattice energies for molecular crystals from experimental crystal structures

SP Thomas, PR Spackman, D Jayatilaka… - Journal of chemical …, 2018 - ACS Publications
Using four different benchmark sets of molecular crystals, we establish the level of
confidence for lattice energies estimated using CE-B3LYP model energies and experimental …

Observations into the reactivity, docking, DFT, and MD simulations of fludarabine and clofarabine in various solvents

G Venkatesh, S Haseena, JS Al-Otaibi, YS Mary… - Journal of Molecular …, 2023 - Elsevier
Abstract Fludarabine (FA) and Clofarabine (FCA) two novel drugs are studied
experimentally and theoretically. The solvation free energies of FA and FCA molecules have …

Conformational Energy Benchmark for Longer n-Alkane Chains

S Ehlert, S Grimme, A Hansen - The Journal of Physical Chemistry …, 2022 - ACS Publications
We present the first benchmark set focusing on the conformational energies of highly
flexible, long n-alkane chains, termed ACONFL. Unbranched alkanes are ubiquitous …

Accurate modeling of organic molecular crystals by dispersion-corrected density functional tight binding (DFTB)

JG Brandenburg, S Grimme - The journal of physical chemistry …, 2014 - ACS Publications
The ambitious goal of organic crystal structure prediction challenges theoretical methods
regarding their accuracy and efficiency. Dispersion-corrected density functional theory (DFT …