Distinct insight into the use of difunctional double-decker silsesquioxanes as building blocks for alternating A–B type macromolecular frameworks

J Duszczak, A Mrzygłód, K Mituła… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Despite the rapid progress in the research on the synthesis of linear macromolecular
systems with double-decker SQs included in the co-polymer chain, based on diverse …

Conjugation in polysiloxane copolymers via unexpected Si-O-Si dπ-pπ overlap, a second mechanism?

JJR Arias, Z Zhang, M Takahashi, P Mahalingam… - Polymer Journal, 2024 - nature.com
We previously reported that functionalized phenyl-and vinyl-silsesquioxanes (SQs) and
[RSiO 1.5] 8, 10, 12 (R= Ph or vinyl) exhibited redshifted absorption and emission …

Conjugation through Si–O–Si bonds, silsesquioxane (SQ) half cage copolymers, extended examples via SiO 0.5/SiO 1.5 units: multiple emissive states in violation of …

Z Zhang, JJR Arias, H Kaehr, Y Liu, R Murata… - Dalton …, 2024 - pubs.rsc.org
We previously reported that phenyl-and vinyl-silsesquioxanes (SQs),[RSiO1. 5] 8, 10, 12 (R=
Ph or vinyl) functionalized with three or more conjugated moieties show red-shifted …

Thiol‐ene polymerization of double‐decker‐shaped phenyl‐substituted silsesquioxanes and thiol monomers

N Watanabe, H Imoto, K Matsukawa… - Journal of Polymer …, 2024 - Wiley Online Library
Polymers incorporating double‐decker‐shaped phenyl‐substituted silsesquioxane (DDSQ)
into the main chain are expected to exhibit excellent thermal stability and significantly …