NMR for Single Ion Magnets
Nuclear Magnetic Resonance is particularly sensitive to the electronic structure of matter
and is thus a powerful tool to characterize in-depth the magnetic properties of a system …
and is thus a powerful tool to characterize in-depth the magnetic properties of a system …
Observability of paramagnetic NMR signals at over 10 000 ppm chemical shifts
We report an experimental observation of 31P NMR resonances shifted by over 10 000 ppm
(meaning percent range, and a new record for solutions), and similar 1H chemical shifts, in …
(meaning percent range, and a new record for solutions), and similar 1H chemical shifts, in …
Modern physical methods for the molecular design of single-molecule magnets
Many paramagnetic metal complexes have emerged as unique magnetic materials (single-
molecule magnets), which behave as conventional magnets at the single-molecule level …
molecule magnets), which behave as conventional magnets at the single-molecule level …
Synthesis, X-ray structure and magnetic properties of the apically functionalized monocapped cobalt (ii) tris-pyridineoximates possessing SMM behaviour
AS Belov, SA Belova, NN Efimov, VV Zlobina… - Dalton …, 2023 - pubs.rsc.org
The title cobalt (II) pseudoclathrochelate complexes possess an intermediate trigonal
prismatic–trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM …
prismatic–trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM …
Selective Pathway toward Heteroleptic Spin-Crossover Iron(II) Complexes with Pyridine-Based N-Donor Ligands
I Nikovskiy, DY Aleshin, VV Novikov… - Inorganic …, 2022 - ACS Publications
A new synthetic pathway is devised to selectively produce previously elusive heteroleptic
iron (II) complexes of terpyridine and N, N′-disubstituted bis (pyrazol-3-yl) pyridines that …
iron (II) complexes of terpyridine and N, N′-disubstituted bis (pyrazol-3-yl) pyridines that …
Solvent-induced encapsulation of cobalt (II) ion by a boron-capped tris-pyrazoloximate
AS Belov, YZ Voloshin, AA Pavlov… - Inorganic …, 2020 - ACS Publications
Boron-cross-linked cobalt (II) pseudoclathrochelate was obtained by the template reaction of
2-acetylpyrazoloxime, phenylboronic acid, and a new DMF cobalt (II) solvato complex with a …
2-acetylpyrazoloxime, phenylboronic acid, and a new DMF cobalt (II) solvato complex with a …
In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes
Y Pankratova, D Aleshin, I Nikovskiy… - Inorganic …, 2020 - ACS Publications
Here we report the first successful attempt to identify spin-crossover compounds in solutions
of metal complexes produced by mixing different ligands and an appropriate metal salt by …
of metal complexes produced by mixing different ligands and an appropriate metal salt by …
Towards the Molecular Design of Spin‐Crossover Complexes of 2, 6‐Bis (pyrazol‐3‐yl) pyridines
The molecular design of spin‐crossover complexes relies on controlling the spin state of a
transition metal ion by proper chemical modifications of the ligands. Herein, the first N, N' …
transition metal ion by proper chemical modifications of the ligands. Herein, the first N, N' …
Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with N,N′-Disubstituted Bis(pyrazol-3-yl)pyridines
Here, we report a combined study of the effects of two chemical modifications to an N, N′-
disubstituted bis (pyrazol-3-yl) pyridine (3-bpp) and of different solvents on the spin …
disubstituted bis (pyrazol-3-yl) pyridine (3-bpp) and of different solvents on the spin …
A quantum chemistry view on two archetypical paramagnetic pentacoordinate nickel (II) complexes offers a fresh look on their NMR spectra
Quantum chemical methods for calculating paramagnetic NMR observables are becoming
increasingly accessible and are being included in the inorganic chemistry practice. Here, we …
increasingly accessible and are being included in the inorganic chemistry practice. Here, we …