Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Transformation of step-growth polymerization into living chain-growth polymerization

T Yokozawa, Y Ohta - Chemical reviews, 2016 - ACS Publications
Conventional condensation polymerization proceeds in a stepgrowth polymerization
manner, and it was thought that “living” condensation polymerization was essentially …

Influence of Backbone Fluorination in Regioregular Poly (3-alkyl-4-fluoro) thiophenes

Z Fei, P Boufflet, S Wood, J Wade… - Journal of the …, 2015 - ACS Publications
We report two strategies toward the synthesis of 3-alkyl-4-fluorothiophenes containing
straight (hexyl and octyl) and branched (2-ethylhexyl) alkyl groups. We demonstrate that …

Recent advances in develo** high-performance organic hole transporting materials for inverted perovskite solar cells

X Sun, Z Zhu, Z Li - Frontiers of optoelectronics, 2022 - Springer
Inverted perovskite solar cells (PVSCs) have recently made exciting progress, showing high
power conversion efficiencies (PCEs) of 25% in single-junction devices and 30.5% in …

A broadly applicable strategy for entry into homogeneous nickel (0) catalysts from air-stable nickel (II) complexes

EA Standley, SJ Smith, P Müller, TF Jamison - Organometallics, 2014 - ACS Publications
A series of air-stable nickel complexes of the form L2Ni (aryl) X (L= monodentate phosphine,
X= Cl, Br) and LNi (aryl) X (L= bis-phosphine) have been synthesized and are presented as …

Universal Suzuki–Miyaura catalyst-transfer polymerization for precision synthesis of strong donor/acceptor-based conjugated polymers and their sequence …

J Lee, H Kim, H Park, T Kim, SH Hwang… - Journal of the …, 2021 - ACS Publications
Catalyst-transfer polymerization has revolutionized the field of polymer synthesis due to its
living character, but for a given catalyst system, the polymer scope is rather narrow. Herein …

The history of palladium-catalyzed cross-couplings should inspire the future of catalyst-transfer polymerization

AK Leone, EA Mueller, AJ McNeil - Journal of the American …, 2018 - ACS Publications
Conjugated polymers are the workhorse materials in organic electronics, a field that is
rapidly growing to encompass energy storage devices such as supercapacitors and …

Highly Efficient Preparation of Length and Width-Controllable Donor–Acceptor Nanoribbons via Polymerization-Induced Crystallization-Driven Self-Assembly of Fully …

H Kim, J Lee, SH Hwang, N Yun, S Park… - Journal of the American …, 2024 - ACS Publications
Despite the high potential of one-dimensional (1D) donor–acceptor (D–A) coaxial
nanostructures in bulk-heterojunction solar cell applications, the preparation of such 1D …

Precision Synthesis of Various Low‐Bandgap Donor–Acceptor Alternating Conjugated Polymers via Living Suzuki–Miyaura Catalyst‐Transfer Polymerization

H Kim, J Lee, T Kim, M Cho, TL Choi - Angewandte Chemie, 2022 - Wiley Online Library
Herein, we demonstrate that living Suzuki–Miyaura catalyst‐transfer polymerization (SCTP)
using a RuPhos Pd G3 precatalyst is a versatile method for the precision synthesis of …