Rotational action spectroscopy of trapped molecular ions

O Asvany, S Schlemmer - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Rotational action spectroscopy is an experimental method in which rotational spectra of
molecules, typically in the microwave to sub-mm-wave domain of the electromagnetic …

Electronic spectroscopy of monocyclic carbon ring cations for astrochemical consideration

J Rademacher, ES Reedy… - The Journal of Physical …, 2022 - ACS Publications
Gas phase electronic spectra of pure carbon cations generated by laser vaporization of
graphite in a supersonic jet and cooled to below 10 K and tagged with helium atoms in a …

Electronic spectra of positively charged carbon clusters—C2n+ (n= 6–14)

JT Buntine, MI Cotter, U Jacovella, C Liu… - The Journal of …, 2021 - pubs.aip.org
Electronic spectra are measured for mass-selected C 2 n+(n= 6–14) clusters over the visible
and near-infrared spectral range through resonance enhanced photodissociation of clusters …

[HTML][HTML] An ion mobility mass spectrometer coupled with a cryogenic ion trap for recording electronic spectra of charged, isomer-selected clusters

JT Buntine, E Carrascosa, JN Bull… - Review of Scientific …, 2022 - pubs.aip.org
Infrared and electronic spectra are indispensable for understanding the structural and
energetic properties of charged molecules and clusters in the gas phase. However, the …

[HTML][HTML] Photoelectron imaging of cryogenically cooled BiO− and BiO2− anions

GS Kocheril, HW Gao, DF Yuan… - The Journal of Chemical …, 2022 - pubs.aip.org
The advent of ion traps as cooling devices has revolutionized ion spectroscopy as it is now
possible to efficiently cool ions vibrationally and rotationally to levels where truly high …

Adsorption of helium on small cationic PAHs: Influence of hydrocarbon structure on the microsolvation pattern

A Schiller, M Meyer, P Martini, F Zappa… - The Journal of …, 2021 - ACS Publications
The adsorption of up to∼ 100 helium atoms on cations of the planar polycyclic aromatic
hydrocarbons (PAHs) anthracene, phenanthrene, fluoranthene, and pyrene was studied by …

Gas-phase electronic spectra of HC 2n+ 1 H+(n= 2–6) chains

SJP Marlton, C Liu, P Watkins, EJ Bieske - … Chemistry Chemical Physics, 2024 - pubs.rsc.org
Highly unsaturated carbon chains are generated in combustion processes and electrical
discharges, and are confirmed constituents of the interstellar medium. In hydrogen-rich …

[HTML][HTML] Communication: Electronic transition of the l–C6+ cation at 417 nm

JE Colley, DS Orr, MA Duncan - The Journal of Chemical Physics, 2022 - pubs.aip.org
A new electronic transition is reported for the linear C 6+ cation with an origin at 416.8 nm.
This spectrum can be compared to the matrix isolation spectra at lower energies reported …

Spectroscopy of astrophysically relevant ions in traps

EK Campbell - Molecular Physics, 2020 - Taylor & Francis
The detection of molecules in the interstellar medium relies on the comparison between
observational and laboratory data recorded under relevant conditions. In this contribution …

Electronic absorptions of C5+ detected in the visible through action spectroscopy in a cryogenic trap

ES Reedy, J Rademacher, R Szabla… - Molecular …, 2022 - Taylor & Francis
The 2 Π g← X 2 Σ u+ electronic spectrum of C 5+ in the gas-phase with origin band at 513
nm is reported following experiments in a cryogenic ion trap** instrument. Buffer gas …