Dithiocarbamate complexes as single source precursors to nanoscale binary, ternary and quaternary metal sulfides

JC Sarker, G Hogarth - Chemical Reviews, 2021 - ACS Publications
Nanodimensional metal sulfides are a develo** class of low-cost materials with potential
applications in areas as wide-ranging as energy storage, electrocatalysis, and imaging. An …

Unravelling the intricacies of solvents and sulfur sources in colloidal synthesis of metal sulfide semiconductor nanocrystals

V Mauritz, RW Crisp - Journal of Materials Chemistry C, 2024 - pubs.rsc.org
Synthetic routes producing colloidal metal sulfide semiconductors vary in mechanism
depending on the sulfur precursor utilized in the reaction. This review provides overarching …

Active nature of primary amines during thermal decomposition of nickel dithiocarbamates to nickel sulfide nanoparticles

N Hollingsworth, A Roffey, HU Islam, M Mercy… - Chemistry of …, 2014 - ACS Publications
Although [Ni (S2CNBui2) 2] is stable at high temperatures in a range of solvents,
solvothermal decomposition occurs at 145° C in oleylamine to give pure NiS nanoparticles …

Microwave-assisted synthesis of PbS nanostructures

DC Onwudiwe - Heliyon, 2019 - cell.com
The synthesis of PbS nanostructures by microwave irradiation of single source precursor
compounds in ethyleneglycol medium is reported. Pb (II) bis (N-ethyl-N …

Scalable and universal route for the deposition of binary, ternary, and quaternary metal sulfide materials from molecular precursors

G Murtaza, S Alderhami, YT Alharbi… - ACS applied energy …, 2020 - ACS Publications
A range of binary, ternary (CFS), and quaternary (CZTS) metal sulfide materials have been
successfully deposited onto the glass substrates by air-spray deposition of metal …

Application of the donor–acceptor concept to intercept low oxidation state group 14 element hydrides using a Wittig reagent as a Lewis base

AK Swarnakar, SM McDonald, KC Deutsch… - Inorganic …, 2014 - ACS Publications
This article outlines our attempts to stabilize the Group 14 element dihydrides, GeH2 and
SnH2, using commonly employed phosphine and pyridine donors; in each case, elemental …

Bis (piperidinedithiocarbamato) pyridinecadmium (II) as a single-source precursor for the synthesis of CdS nanoparticles and aerosol-assisted chemical vapour …

S Mlowe, DJ Lewis, MA Malik, J Raftery… - New Journal of …, 2014 - pubs.rsc.org
The synthesis and single-crystal X-ray structure of bis (piperidinedithiocarbamato)
pyridinecadmium (II),[Cd (S2C (NC5H10)) 2 (NC5H5)] are reported and its use as a …

CdS nanocapsules and nanospheres as efficient solar light-driven photocatalysts for degradation of Congo red dye

A Khan, R Khan, A Waseem, A Iqbal, ZH Shah - Inorganic Chemistry …, 2016 - Elsevier
Abstract CdS-1 (nanosphers) and CdS-2 (nanocapsule), were synthesized via green
synthetic route without using any toxic surfactants by thermolysis of bis (4 …

Synthesis of ternary sulfide nanomaterials using dithiocarbamate complexes as single source precursors

A Roffey, N Hollingsworth, G Hogarth - Nanoscale Advances, 2019 - pubs.rsc.org
We report the use of cheap, readily accessible and easy to handle di-isobutyl-
dithiocarbamate complexes,[M (S2CNiBu2) n], as single source precursors (SSPs) to ternary …

Recent progress in chiral inorganic nanostructures

J Govan, YK Gun'Ko - 2016 - books.rsc.org
Chirality plays an important role in the fields of chemistry, pharmacology, biology and
medicine. Recently, chirality has also been envisaged to play an important role in …