The positive muon and μSR spectroscopy: powerful tools for investigating the structure and dynamics of free radicals and spin probes in complex systems
I McKenzie - Annual Reports Section" C"(Physical Chemistry), 2013 - pubs.rsc.org
The positive muon (μ+) can be incorporated into free radicals where it acts as a probe of the
structure and dynamics. The muoniated radicals are characterized by a series of magnetic …
structure and dynamics. The muoniated radicals are characterized by a series of magnetic …
Kinetics of the reaction between H and superheated water probed with muonium
CD Alcorn, JC Brodovitch, PW Percival, M Smith… - Chemical Physics, 2014 - Elsevier
Safe operation of supercritical water-cooled reactors requires knowledge of the kinetics of
transient species formed by the radiolysis of water in the range 300–650° C. Using …
transient species formed by the radiolysis of water in the range 300–650° C. Using …
Slowing-down times and stop** powers for in low-pressure gases
M Senba, DJ Arseneau, JJ Pan, DG Fleming - Physical Review A—Atomic …, 2006 - APS
The times taken by positive muons (μ+) to slow down from initial energies in the range∼ 3 to
1 MeV, to the energy of the last muonium formation,≈ 10 eV, at the end of cyclic charge …
1 MeV, to the energy of the last muonium formation,≈ 10 eV, at the end of cyclic charge …
Prediction of rate constants of important chemical reactions in water radiation chemistry in sub and supercritical water–non-equilibrium reactions
G Liu, C Landry, K Ghandi - Canadian Journal of Chemistry, 2018 - cdnsciencepub.com
The rate constants for reactions involved in the radiolysis of water under relevant
thermodynamic conditions in supercritical water-cooled reactors are estimated for inputs in …
thermodynamic conditions in supercritical water-cooled reactors are estimated for inputs in …
Enolization of acetone in superheated water detected via radical formation
K Ghandi, B Addison-Jones… - Journal of the …, 2003 - ACS Publications
Muoniated free radicals have been detected in muon-irradiated aqueous solutions of
acetone at high temperatures and pressures. At temperatures below 250° C, the radical …
acetone at high temperatures and pressures. At temperatures below 250° C, the radical …
Near-diffusion-controlled reactions of muonium in sub-and supercritical water
K Ghandi, B Addison-Jones, JC Brodovitch… - Physical Chemistry …, 2002 - pubs.rsc.org
Rate constants are reported for near-diffusion-controlled reactions of muonium in sub-and
supercritical water. Specifically, the spin-exchange interaction of muonium with Ni2+ and the …
supercritical water. Specifically, the spin-exchange interaction of muonium with Ni2+ and the …
Organic free radicals in superheated water studied by muon spin spectroscopy
There is a pressing need to identify and monitor reaction intermediates in water at high
temperatures and pressures, but conventional techniques have limited capability for …
temperatures and pressures, but conventional techniques have limited capability for …
Prediction of rate constants of important reactions in water radiation chemistry in sub-and supercritical water: Equilibrium reactions
G Liu, T Du, L Toth, J Beninger… - CNL Nuclear Review …, 2016 - inis.iaea.org
[en] Various studies have shown that rate constants of many reactions in water go through a
plateau before reaching the critical point. In 2002, Ghandi et al. proposed a model that …
plateau before reaching the critical point. In 2002, Ghandi et al. proposed a model that …
Laser-muon spin spectroscopy in liquids—A technique to study the excited state chemistry of transients
K Ghandi, IP Clark, JS Lord, SP Cottrell - Physical Chemistry Chemical …, 2007 - pubs.rsc.org
This study introduces laser-muon spin spectroscopy in the liquid phase, which extends
muonium chemistry in liquids to the realm of excited states and enables the detection of …
muonium chemistry in liquids to the realm of excited states and enables the detection of …
Muon implantation in inert gases studied by radio frequency spectroscopy
Diamagnetic and muonium (Mu) fractions formed in low-pressure inert gases, by energetic
muon implantation, have been studied using the technique of time-delayed radio frequency …
muon implantation, have been studied using the technique of time-delayed radio frequency …