Halogenated triarylboranes (BAr3) have been known for decades, however it has only been
since the surge of interest in main group catalysis that their application as strong Lewis acid …

Research on chlorine‐free conversions of P4 into organophosphorus compounds (OPCs)
has a long track record, but methods that allow desirable, direct P− C bond formations have …

The reactivity of two paramagnetic nickel (I) compounds, CpNi (NHC)(where Cp=
cyclopentadienyl; NHC= 1, 3‐bis (2, 4, 6‐trimethylphenyl) imidazol‐2‐ylidene (IMes) or 1, 3 …

Reaktionen der paramagnetischen Nickel (I)‐Verbindungen CpNi (NHC)(Cp=
Cyclopentadienyl; NHC= 1, 3‐Bis (2, 4, 6‐trimethylphenyl) imidazol‐2‐yliden (IMes) bzw. 1 …

The direct construction of functionalized diphosphine ligands from P4 is a highly valuable
but challenging transformation. In this work, a simple method has been developed for the …

A family of cis-macrocyclic diphosphines was prepared in just three steps from white
phosphorus and commercial materials using a modular synthetic approach. Alkylation of …

This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

The reactivity of diazadiphosphapentalene 1 towards various substrates was investigated.
Reaction of 1 with ammonia–borane resulted in transfer hydrogenolysis concomitantly with …

(Me3Si) 2NPCl2, which is formally capable of eliminating two equivalents of Me3SiCl, is
shown to be a suitable starting material to prepare highly reactive PN species by successive …

Abstract The one‐step synthesis (33% isolated yield) of a novel bicyclic diphosphane,[P
(CH2) 2NC6H4 (4‐NMe2)] 2, P− P (NMe2), from the reaction of [P (CH2OH) 4] Cl and …