Metal–organic derivatives with fluorinated ligands as precursors for inorganic nanomaterials

S Mishra, S Daniele - Chemical Reviews, 2015 - ACS Publications
Inorganic nanomaterials cover a wide range of applications in electronics, optics,
magnetism, catalysis, biomedical, and environmental issues. 1− 3 The properties of these …

'Old Chemistries' for new applications: Perspectives for development of precursors for MOCVD and ALD applications

A Devi - Coordination chemistry reviews, 2013 - Elsevier
The concept of the transformation of molecules to materials has been well established in the
field of chemical vapor deposition (CVD) and atomic layer deposition (ALD). However …

Rare-earth beta-diketonates

K Binnemans - Handbook on the physics and chemistry of rare earths, 2005 - Elsevier
Rare-earth β-diketonates are complexes of β-diketones (1, 3-diketones) with rare-earth ions.
These complexes are the most popular and the most intensively investigated rare-earth …

Engineering of molecular architectures of β-diketonate precursors toward new advanced materials

GG Condorelli, G Malandrino, IL Fragalà - Coordination chemistry reviews, 2007 - Elsevier
Metal complexes bearing linked hexafluoroacetylacetonates and ancillary Lewis ligands,
have found wide interest as precursors for metal-organic chemical vapor deposition …

Metal-radical coordination complexes of thiazyl and selenazyl ligands

KE Preuss - Coordination Chemistry Reviews, 2015 - Elsevier
The so-called “metal-radical approach” to the design of molecule-based magnetic materials
relies on the availability of paramagnetic ligands that can reliably form coordination …

Synthesis and characterization of liquid MOCVD precursors for thin films of cadmium oxide

A Gulino, P Dapporto, P Rossi, I Fragala - Chemistry of materials, 2002 - ACS Publications
Four novel Cd (C5F6HO2) 2⊙ polyether adducts were prepared through simple procedures
with stoichiometric quantities of cadmium oxide, hexafluoroacetylacetone C5F6H2O2, and …

Direct Synthesis of Hexagonal NaGdF4 Nanocrystals from a Single‐Source Precursor: Upconverting NaGdF4:Yb3+,Tm3+ and Its Composites with TiO2 for Near …

Y Chen, S Mishra, G Ledoux… - Chemistry–An Asian …, 2014 - Wiley Online Library
A novel single‐source precursor NaGd (TFA) 4 (diglyme)(TFA= trifluoroacetate) was
synthesized, characterized thoroughly, and used to obtain the hexagonal phase of NaGdF4 …

Synthesis and characterization of volatile, fluorine-free β-ketoiminate lanthanide MOCVD precursors and their implementation in low-temperature growth of epitaxial …

NL Edleman, A Wang, JA Belot, AW Metz… - Inorganic …, 2002 - ACS Publications
A new class of volatile, low-melting, fluorine-free lanthanide metal− organic chemical vapor
deposition (MOCVD) precursors has been developed. The neutral, monomeric Ce, Nd, Gd …

Lanthanide “second-generation” precursors for MOCVD applications: Effects of the metal ionic radius and polyether length on coordination spheres and mass …

G Malandrino, IL Fragalà - Coordination chemistry reviews, 2006 - Elsevier
The panorama of trishexafluoroacetylacetonato polyether complexes of rare-earth metals is
considered. The methods of preparation have been classified according to the nature of the …

[HTML][HTML] A Facile One-Pot Approach to the Synthesis of Gd-Eu Based Metal-Organic Frameworks and Applications to Sensing of Fe3+ and Cr2O72− Ions

R Puglisi, AL Pellegrino, R Fiorenza, S Scirè… - Sensors, 2021 - mdpi.com
Gadolinium metal-organic frameworks (Gd-MOFs) and Eu-doped Gd-MOFs have been
synthesized through a one-pot green approach using commercially available reagents. The …