Numerical techniques for the solution of the molecular weight distribution in polymerization mechanisms, state of the art

E Saldívar‐Guerra - Macromolecular Reaction Engineering, 2020 - Wiley Online Library
The molecular weight distribution (MWD) is possibly the most important characteristic of a
polymer. Polymers derive many of their physical properties from their MWD. Therefore, since …

Slurry-phase ethylene polymerization processes: a review on multiscale modeling and simulations

AK Thakur, SK Gupta, P Chaudhari - Reviews in Chemical …, 2022 - degruyter.com
Slurry polymerization processes using Zeigler–Natta catalysts, are most widely used for the
production of polyethylene due to their several advantages over other processes. Significant …

A novel method for dynamic molecular weight distribution determination in organometallic catalyzed olefin polymerizations

M Shiri, M Parvazinia, AA Yousefi, N Bahri-Laleh… - Catalysts, 2022 - mdpi.com
In this study, a mathematical model for the time evolution of molecular weight distribution
(MWD) was developed. This temporal model is based on the well-known Ziegler–Natta …

An effectiveness factor model for slurry phase olefin polymerizations

S Zhang, Q Zhang, B Kong, C Yang, RO Fox - Chemical Engineering …, 2022 - Elsevier
The multigrain model (MGM) is the most widely used single-particle model, giving a detailed
description of phenomena during olefin polymerization. However, the detailed modeling of …

Steady-state and dynamic modeling of the solution polyethylene process based on rigorous PC-SAFT equation of state

SX Ruan, XB Zhang, ZH Luo - Industrial & Engineering Chemistry …, 2022 - ACS Publications
This work aims to perform steady-state and dynamic modeling of an industrial solution
polyethylene process. The phase behaviors in reactors under various conditions were …

Modeling and simulation of an industrial slurry phase ethylene polymerization reactor: effect of reactor operating variables

AK Thakur, SK Gupta, P Chaudhari - Iranian Polymer Journal, 2020 - Springer
A hierarchical and computationally efficient mathematical model was developed to explain
the polymerization of high-density polyethylene (HDPE) in an isothermal, industrial …

Model-Based design of a novel process applicable to solution and slurry polymerization with phase change

XB Zhang, K Wang, D Wang, G Yang, Y Gao… - Chemical Engineering …, 2024 - Elsevier
This work aims on develo** a novel process that is applicable to solution and slurry
polymerization, which can efficiently control production efficiency, product properties and …

Modeling of Slurry Phase Olefin Polymerizations in a Semibatch Well-Mixed Stirred Tank: Effect of Mass Transfer

S Zhang, Z Jia, B Kong, S Ma, ZS Mao… - Industrial & …, 2023 - ACS Publications
A multiscale model of slurry-phase olefin polymerization is developed by extending the
multigrain model to account for the existence of gas–liquid mass transfer resistance in an …

Scale up of reactor recipes for bimodal high-density polyethylene production in cascade process

AG Fisch - Reaction Chemistry & Engineering, 2023 - pubs.rsc.org
New bimodal high-density polyethylene (HDPE) resins are commonly developed in pilot
plants. Among multiple goals, the tests aim to determine the operational conditions of the …

Exploring bimodal HDPE synthesis using single-and dual-site metallocene catalysts: a comprehensive review of the Monte Carlo method and AI-based approaches

RB Habashi, M Najafi, R Zarghami - Journal of Polymer Research, 2024 - Springer
The alteration of the molecular weight distribution (MWD) in high-density polyethylenes
(HDPEs) can effectively address processing challenges. However, widening the MWD may …