In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Aliphatic allylic amines are found in a great variety of complex and biorelevant molecules.
The direct allylic C–H amination of alkenes serves as the most straightforward method …

Three-component carboacylation of simple alkenes with readily available reagents is
challenging. Transition metal-catalysed intermolecular carboacylation works for alkenes with …

The construction of carbon–heteroatom bonds is one of the most active areas of research in
organic chemistry because the function of organic molecules is often derived from the …

We report the first palladium hydride enabled hydroalkenylation of strained molecules. This
new mild protocol proceeds via a regio-and chemoselective hydropalladation step, followed …

Radical‐involved multicomponent difunctionalization of 1, 3‐dienes has recently emerged
as a promising strategy for rapid synthesis of valuable allylic compounds in one‐pot …

Transition metal-catalysed allylic functionalization reactions have been established as a
central synthetic transformation to enable the construction of carbon–carbon and carbon …

Kharasch–Sosnovsky reaction is one of the most powerful methods for allylic oxidation of
alkenes. However, the inherent radical mechanism and use of peroxides as both oxidants …