Diradicals

M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

Solid-state NMR investigations of extracellular matrixes and cell walls of algae, bacteria, fungi, and plants

N Ghassemi, A Poulhazan, F Deligey… - Chemical …, 2021 - ACS Publications
Extracellular matrixes (ECMs), such as the cell walls and biofilms, are important for
supporting cell integrity and function and regulating intercellular communication. These …

[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …

Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR

T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …

Atomic-level structure determination of amorphous molecular solids by NMR

M Cordova, P Moutzouri, SO Nilsson Lill… - Nature …, 2023 - nature.com
Abstract Structure determination of amorphous materials remains challenging, owing to the
disorder inherent to these materials. Nuclear magnetic resonance (NMR) powder …

Dynamic nuclear polarization surface enhanced NMR spectroscopy

AJ Rossini, A Zagdoun, M Lelli, A Lesage… - Accounts of chemical …, 2013 - ACS Publications
Many of the functions and applications of advanced materials result from their interfacial
structures and properties. However, the difficulty in characterizing the surface structure of …

Highly efficient, water‐soluble polarizing agents for dynamic nuclear polarization at high frequency

C Sauvée, M Rosay, G Casano… - Angewandte Chemie …, 2013 - Wiley Online Library
Dynamic nuclear polarization coupled to solid-state NMR spectroscopy (DNP/ssNMR) is
emerging as a very powerful technique to overcome the limitations resulting from the …

Solid-state NMR spectroscopy

B Reif, SE Ashbrook, L Emsley, M Hong - Nature Reviews Methods …, 2021 - nature.com
Solid-state nuclear magnetic resonance (NMR) spectroscopy is an atomic-level method to
determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This …

NMR spectroscopy probes microstructure, dynamics and do** of metal halide perovskites

DJ Kubicki, SD Stranks, CP Grey… - Nature Reviews Chemistry, 2021 - nature.com
Solid-state magic-angle spinning NMR spectroscopy is a powerful technique to probe
atomic-level microstructure and structural dynamics in metal halide perovskites. It can be …