Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …

Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …

The β-diketiminate-stabilized calcium amide complex [{ArNC (Me) CHC (Me) NAr} Ca {N
(SiMe3) 2}(THF)](Ar= 2, 6-diisopropylphenyl) and magnesium methyl complex [{ArNC (Me) …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

The aim of this review is to highlight how the diversity generated by N-substitution in the well-
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …

Reaction of SrI2, EuI2 (THF) 2, and YbI2 (THF) 2 with KN (SiMe3) 2 and [{(i Pr) 2ATI} K]((i Pr)
2ATI= N-isopropyl-2-(isopropylamino) troponiminate) led to monoaminotroponiminate …

Abstract [{N^ N} M (X)(thf) n] alkyl (X= CH (SiMe3) 2) and amide (X= N (SiMe3) 2) complexes
of alkaline earths (M= Ca, Sr, Ba) and divalent rare earths (YbII and EuII) bearing an …

The large alkaline earths (Ae), calcium, strontium and barium, have in the past 15 years
yielded a brand new generation of heteroleptic molecular catalysts for the production of fine …

The rare earth metal dichlorides [(1) MCl2 (THF) 3](2a, M= Sc; 2b, M= Y; 2c, M= Lu) and the
gadolinium complex [(1) GdCl2 (THF) 2]·[LiCl (THF) 2](2d), containing the 1, 3-bis (2, 6 …