Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Industrial carbon dioxide capture and utilization: state of the art and future challenges

W Gao, S Liang, R Wang, Q Jiang, Y Zhang… - Chemical Society …, 2020 - pubs.rsc.org
Dramatically increased CO2 concentration from several point sources is perceived to cause
severe greenhouse effect towards the serious ongoing global warming with associated …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol

D Li, F Xu, X Tang, S Dai, T Pu, X Liu, P Tian, F Xuan… - Nature Catalysis, 2022 - nature.com
The surface structure of heterogeneous catalysts is closely associated with their catalytic
performance. Current efforts for structural modification mainly focus on improving the catalyst …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H **n, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Engineering the Cu/Mo2CTx (MXene) interface to drive CO2 hydrogenation to methanol

H Zhou, Z Chen, AV López, ED López, E Lam… - Nature Catalysis, 2021 - nature.com
Abstract Development of efficient catalysts for the direct hydrogenation of CO2 to methanol is
essential for the valorization of this abundant feedstock. Here we show that a silica …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis

X Jiang, X Nie, X Guo, C Song, JG Chen - Chemical reviews, 2020 - ACS Publications
The utilization of fossil fuels has enabled an unprecedented era of prosperity and
advancement of well-being for human society. However, the associated increase in …

State of the art and perspectives in heterogeneous catalysis of CO 2 hydrogenation to methanol

J Zhong, X Yang, Z Wu, B Liang, Y Huang… - Chemical Society …, 2020 - pubs.rsc.org
The ever-increasing amount of anthropogenic carbon dioxide (CO2) emissions has resulted
in great environmental impacts. The selective hydrogenation of CO2 to methanol, the first …