Metal–organic frameworks as a platform for clean energy applications
Abstract Metal–organic frameworks (MOFs), an emerging class of porous materials, have
shown intriguing and promising properties in a wide range of applications due to their …
shown intriguing and promising properties in a wide range of applications due to their …
Analysis of electrocatalytic metal-organic frameworks
The electrochemical analysis of molecular catalysts for the conversion of bulk feedstocks
into energy-rich clean fuels has seen dramatic advances in the last decade. More recently …
into energy-rich clean fuels has seen dramatic advances in the last decade. More recently …
Effects of covalency on anionic redox chemistry in semiquinoid-based metal–organic frameworks
Two iron–semiquinoid framework materials,(H2NMe2) 2Fe2 (Cl2 dhbq) 3 (1) and (H2NMe2)
4Fe3 (Cl2 dhbq) 3 (SO4) 2 (Cl2 dhbq n–= deprotonated 2, 5-dichloro-3, 6 …
4Fe3 (Cl2 dhbq) 3 (SO4) 2 (Cl2 dhbq n–= deprotonated 2, 5-dichloro-3, 6 …
From molecules to porous materials: Integrating discrete electrocatalytic active sites into extended frameworks
Metal–organic and covalent–organic frameworks can serve as a bridge between the realms
of homo-and heterogeneous catalytic systems. While there are numerous molecular …
of homo-and heterogeneous catalytic systems. While there are numerous molecular …
Redox-active benzoquinones as challenging “non-innocent” linkers to construct 2D frameworks and nanostructures with tunable physical properties
N Monni, MS Angotzi, M Oggianu… - Journal of Materials …, 2022 - pubs.rsc.org
Exploiting redox activity in supramolecular frameworks such as coordination polymers, metal–
organic frameworks and related nanostructures is of paramount importance both at the …
organic frameworks and related nanostructures is of paramount importance both at the …
Coordination-driven self-assembly of anthraquinone-based metal–organic cages for photocatalytic selective [2+ 2] cycloaddition
Visible-light-promoted [2+ 2] cycloaddition provides a straightforward and efficient way to
produce cyclobutanes, which are the core skeleton in commercial pharmaceuticals and fine …
produce cyclobutanes, which are the core skeleton in commercial pharmaceuticals and fine …
Bulk-to-surface proton-coupled electron transfer reactivity of the metal–organic framework MIL-125
CT Saouma, S Richard, S Smolders… - Journal of the …, 2018 - ACS Publications
Stoichiometric proton-coupled electron transfer (PCET) reactions of the metal–organic
framework (MOF) MIL-125, Ti8O8 (OH) 4 (bdc) 6 (bdc= terephthalate), are described. In the …
framework (MOF) MIL-125, Ti8O8 (OH) 4 (bdc) 6 (bdc= terephthalate), are described. In the …
Proton coupled electron transfer: novel photochromic performance in a host–guest collaborative MOF
Z Shao, Q Wu, X Han, Y Zhao, Q **e, H Wang… - Chemical …, 2019 - pubs.rsc.org
Proton coupled electron transfer: novel photochromic performance in a host–guest collaborative
MOF - Chemical Communications (RSC Publishing) DOI:10.1039/C9CC05498G Royal Society …
MOF - Chemical Communications (RSC Publishing) DOI:10.1039/C9CC05498G Royal Society …
Proton conductivity and sorption study in three sulfonic group functionalized mixed ligand coordination polymers and the impact of structural dynamicity on their …
Two new mixed ligand coordination polymers (CPs) that are sulfonic group functionalized,
namely,{[Cd (bpe) 0.5 (5-sip)(H2O)]· 4H2O (bpeH2) 0.5} n (1) and {[Cd1. 5 (bte)(5-sip)(H2O) …
namely,{[Cd (bpe) 0.5 (5-sip)(H2O)]· 4H2O (bpeH2) 0.5} n (1) and {[Cd1. 5 (bte)(5-sip)(H2O) …
On the limit of proton-coupled electronic do** in a Ti (iv)-containing MOF
TiIV-containing metal–organic frameworks are known to accumulate electrons in their
conduction bands, accompanied by protons, when irradiated in the presence of alcohols …
conduction bands, accompanied by protons, when irradiated in the presence of alcohols …