Functional polymeric materials based on main‐group elements

F Vidal, F Jäkle - Angewandte Chemie International Edition, 2019 - Wiley Online Library
The past decade has witnessed tremendous advances in the synthesis of polymers that
contain elements from the main groups beyond those found in typical organic polymers …

Do** the Backbone of π‐Conjugated Polymers with Tricoordinate Boron: Synthetic Strategies and Emerging Applications

H Helten - Chemistry–An Asian Journal, 2019 - Wiley Online Library
The do** of π‐conjugated organic compounds with trivalent boron atoms produces
materials with intriguing properties and functions that result from the interaction of the π …

Tetramerization of BEB-Doped Phenalenyls to Obtain (BE)8-[16]Annulenes (E = N, O)

AS Scholz, M Bolte, A Virovets… - Journal of the …, 2024 - ACS Publications
Two (BE) 8-[16] annulenes were prepared and fully characterized by experimental and
quantum-chemical means (1, E= N; 2, E= O). The 1, 8-naphthalenediyl-bridged diborane (6) …

Poly(p‐phenylene iminoborane): A Boron–Nitrogen Analogue of Poly(p‐phenylene vinylene)

T Lorenz, M Crumbach, T Eckert, A Lik… - Angewandte Chemie …, 2017 - Wiley Online Library
Substitution of selected CC units in π‐conjugated organic frameworks by their isoelectronic
and isosteric BN units (BN/CC isosterism) has proven to be a successful concept for the …

NBN‐Doped Conjugated Polycyclic Aromatic Hydrocarbons as an AIEgen Class for Extremely Sensitive Detection of Explosives

WM Wan, D Tian, YN **g, XY Zhang… - Angewandte Chemie …, 2018 - Wiley Online Library
A simple and efficient synthesis of NBN‐doped conjugated polycyclic aromatic
hydrocarbons (such as diazaborinines) has been accomplished by a catalyst‐free …

Poly (arylene iminoborane) s, Analogues of Poly (arylene vinylene) with a BN‐Doped Backbone: A Comprehensive Study

M Maier, J Chorbacher, A Hellinger… - … A European Journal, 2023 - Wiley Online Library
Despite the great success of the concept of do** organic compounds with BN units to
access new materials with tailored properties, its use in polymer chemistry has only been …

Catalytic B–C coupling by Si/B exchange: A versatile route to π-conjugated organoborane molecules, oligomers, and polymers

A Lik, L Fritze, L Müller, H Helten - Journal of the American …, 2017 - ACS Publications
Conjugated organoboranes have emerged as attractive hybrid materials for optoelectronic
applications. Herein, a highly efficient, environmentally benign catalytic B–C bond formation …

Regioselective Functionalization of Stable BN‐Modified Luminescent Tetraphenes for High‐Resolution Fingerprint Imaging

H Huang, Y Zhou, M Wang, J Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
A series of novel BN tetraphene derivatives have been prepared successfully for the first
time via a post‐functionalization strategy. The optical and electronic properties of these …

Poly (thiophene iminoborane): A Poly (thiophene vinylene)(PTV) Analogue with a Fully B N‐Doped Backbone

J Chorbacher, M Maier, J Klopf, M Fest… - Macromolecular Rapid …, 2023 - Wiley Online Library
An unprecedented poly (thiophene iminoborane)—a boron–nitrogen analogue of the well‐
established conjugated organic polymer poly (thiophene vinylene)—is presented. The …

Boron nitride-doped polyphenylenic organogels

J Dosso, H Oubaha, F Fasano, S Melinte… - Chemistry of …, 2022 - ACS Publications
Herein, we describe the synthesis of the first boron nitride-doped polyphenylenic material
obtained through a [4+ 2] cycloaddition reaction between a triethynyl borazine unit and a …