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Capturing photochemical and photophysical transformations in iron complexes with ultrafast X-ray spectroscopy and scattering
KJ Gaffney - Chemical science, 2021 - pubs.rsc.org
Light-driven chemical transformations provide a compelling approach to understanding
chemical reactivity with the potential to use this understanding to advance solar energy and …
chemical reactivity with the potential to use this understanding to advance solar energy and …
[HTML][HTML] A comparative review of time-resolved x-ray and electron scattering to probe structural dynamics
The structure of molecules, particularly the dynamic changes in structure, plays an essential
role in understanding physical and chemical phenomena. Time-resolved (TR) scattering …
role in understanding physical and chemical phenomena. Time-resolved (TR) scattering …
Enhancing electrochemiluminescence efficiency through introducing atomically dispersed ruthenium in nickel-based metal–organic frameworks
G Zhao, X Dong, Y Du, N Zhang, G Bai, D Wu… - Analytical …, 2022 - ACS Publications
The successful application of electrochemiluminescence (ECL) in various fields required
continuous exploration of novel ECL signal emitters. In this work, we have proposed a …
continuous exploration of novel ECL signal emitters. In this work, we have proposed a …
An ultrafast Na-ion battery chemistry through coupling sustainable organic electrodes with modulated aqueous electrolytes
Rechargeable Na-ion batteries for grid-scale applications require key battery materials that
couple high performance with sustainability. However, there are limited choices of …
couple high performance with sustainability. However, there are limited choices of …
Revealing Excited‐State Trajectories on Potential Energy Surfaces with Atomic Resolution in Real Time
Photoexcited molecular trajectories on potential energy surfaces (PESs) prior to
thermalization are intimately connected to the photochemical reaction outcome. The excited …
thermalization are intimately connected to the photochemical reaction outcome. The excited …
High-spin state of a ferrocene electron donor revealed by optical and X-ray transient absorption spectroscopy
Ferrocene is one of the most common electron donors, and map** its ligand-field excited
states is critical to designing donor–acceptor (D–A) molecules with long-lived charge …
states is critical to designing donor–acceptor (D–A) molecules with long-lived charge …
Ultrafast X-ray probes of elementary molecular events
Elementary events that determine photochemical outcomes and molecular functionalities
happen on the femtosecond and subfemtosecond timescales. Among the most ubiquitous …
happen on the femtosecond and subfemtosecond timescales. Among the most ubiquitous …
Solvent-dependent structural dynamics in the ultrafast photodissociation reaction of triiodide observed with time-resolved x-ray solution scattering
Resolving the structural dynamics of bond breaking, bond formation, and solvation is
required for a deeper understanding of solution-phase chemical reactions. In this work, we …
required for a deeper understanding of solution-phase chemical reactions. In this work, we …
Ferricyanide photo-aquation pathway revealed by combined femtosecond Kβ main line and valence-to-core x-ray emission spectroscopy
Reliably identifying short-lived chemical reaction intermediates is crucial to elucidate
reaction mechanisms but becomes particularly challenging when multiple transient species …
reaction mechanisms but becomes particularly challenging when multiple transient species …
Photoinduced dynamics in solution is governed by mutual solute–solvent interactions, which
give rise to phenomena like solvatochromism, the Stokes shift, dual fluorescence, or charge …
give rise to phenomena like solvatochromism, the Stokes shift, dual fluorescence, or charge …