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HFIP in organic synthesis
1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …
Recent progress in synthetic applications of hypervalent iodine (III) reagents
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …
Progress in organocatalysis with hypervalent iodine catalysts
Hypervalent iodine compounds as environmentally friendly and relatively inexpensive
reagents have properties similar to transition metals. They are employed as alternatives to …
reagents have properties similar to transition metals. They are employed as alternatives to …
[HTML][HTML] Mechanochemical synthesis of small organic molecules
With the growing interest in renewable energy and global warming, it is important to
minimize the usage of hazardous chemicals in both academic and industrial research …
minimize the usage of hazardous chemicals in both academic and industrial research …
Recent advances in C–H activation for the synthesis of π-extended materials
The activation of typically unreactive aromatic C–H bonds by transition-metal catalysis has
been receiving increased attention from the synthetic chemistry community in recent years …
been receiving increased attention from the synthetic chemistry community in recent years …
Synthesis of nitrogen‐containing polyaromatics by aza‐annulative π‐extension of unfunctionalized aromatics
Nitrogen‐containing polycyclic aromatic compounds (N‐PACs) are an important class of
compounds in materials science. Reported here is a new aza‐annulative π‐extension (aza …
compounds in materials science. Reported here is a new aza‐annulative π‐extension (aza …
Regiodivergent C–N Coupling of Quinazolinones Controlled by the Dipole Moments of Tautomers
Herein, we report that the dipole moments of tautomers can be the controlling factor for
regiodivergent synthesis of either 14 H-quinazolino [3, 2-f] phenanthridin-14-ones or 6 H …
regiodivergent synthesis of either 14 H-quinazolino [3, 2-f] phenanthridin-14-ones or 6 H …
Recent Advances in Intramolecular Metal‐Free Oxidative C–H Bond Aminations Using Hypervalent Iodine (III) Reagents
S Reddy Kandimalla… - European Journal of …, 2019 - Wiley Online Library
Hypervalent iodine chemistry is a rapidly growing area of research with tremendous impact
on synthetic chemistry in the past years. A rich and diverse chemistry is now available for …
on synthetic chemistry in the past years. A rich and diverse chemistry is now available for …
Nitrenium ions from amine‐iodine (III) combinations
Hypervalent iodine compounds are known for their extensive use as potential oxidants in
organic synthesis. In spite of the similar reactivity with transition metals, hypervalent iodine …
organic synthesis. In spite of the similar reactivity with transition metals, hypervalent iodine …
Strategies to Control Hypervalent Iodine–Primary Amine Reactions
The field of hypervalent iodine chemistry has been prevalent since 1886. Its journey from
obscurity to coming into the limelight has witnessed many effective transformations which …
obscurity to coming into the limelight has witnessed many effective transformations which …