Multimetallic catalysis based on heterometallic complexes and clusters

P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

Hemilability of hybrid ligands and the coordination chemistry of oxazoline‐based systems

P Braunstein, F Naud - Angewandte Chemie International …, 2001 - Wiley Online Library
Ligand design is becoming an increasingly important part of the synthetic activity in
chemistry. This is of course because of the subtle control that ligands exert on the metal …

Catalytic applications of early/late heterobimetallic complexes

BG Cooper, JW Napoline, CM Thomas - Catalysis Reviews, 2012 - Taylor & Francis
Transition metal complexes that combine electronically different metals are most readily
designed by combining an early transition metal and a late transition metal, typically via a …

Aggregation-induced barrier to oxygen—a new AIE mechanism for metal clusters with phosphorescence

Y **, QC Peng, S Li, HF Su, P Luo… - National Science …, 2022 - academic.oup.com
Metal clusters are useful phosphors, but highly luminescent examples are quite rare.
Usually, the phosphorescence of metal clusters is hindered by ambient O2 molecules …

Transition metal chain complexes supported by soft donor assembling ligands

P Braunstein, AA Danopoulos - Chemical Reviews, 2021 - ACS Publications
The chemistry of discrete molecular chains constituted by metals in low oxidation states,
displaying metal–metal proximity and stabilized by suitable metal-bridging, assembling …

Synthesis, structure, photophysics, and excited-state redox properties of the novel luminescent tetranuclear acetylidocopper (I) complex [Cu4 (μ-dppm) 4 (μ4-η1, η2-C …

VWW Yam, WKM Fung, KK Cheung - Angewandte Chemie-International …, 1996 - hub.hku.hk
A strong reducing power in the excited state is just one of the features of the tetranuclear
copper (I) complex 1. It contains an acetylide dianion bridging four copper atoms in both η 1 …

Heterobimetallic Trihydrido Complex of Ruthenium and Rhodium Supported by Cyclopentadienyl Groups with Different Steric Demands

T Takao, T Monoe, R Shimogawa, K Nakamura - Organometallics, 2023 - ACS Publications
The reactivity of heterobimetallic trihydrido complexes of Ru and Rh supported by two kinds
of cyclopentadienyl groups that provide steric differentiation in the dinuclear reaction …

Synthetic, Structural, Spectroscopic, and Theoretical Studies of Structural Isomers of the Cluster Pt3(μ-PPh2)3Ph(PPh3)2. A Unique Example of Core Isomerism in …

R Bender, P Braunstein, A Dedieu, PD Ellis… - Inorganic …, 1996 - ACS Publications
Two isomers of the phosphido-bridged platinum cluster Pt3 (μ-PPh2) 3Ph (PPh3) 2 (2 and 3)
have been isolated, and their structures have been solved by single-crystal X-ray diffraction …

Synthesis, Luminescence, and Electrochemistry of Mix-Capped Trinuclear Copper(I) Acetylide Complexes. X-ray Crystal Structures of [Cu3(μ-dppm)331-C⋮CC6H4OMe-p)(μ31-C⋮CC6H4OEt-p)]PF6 and [Cu3(μ-dppm)331-C⋮CC6H4 …

VWW Yam, WKM Fung, KK Cheung - Organometallics, 1998 - ACS Publications
Two luminescent mix-capped trinuclear copper (I) acetylide complexes,[Cu3 (μ-dppm) 3 (μ3-
η1-C⋮ CC6H4OMe-p)(μ3-η1-C⋮ CC6H4OEt-p)] PF6 (1) and [Cu3 (μ-dppm) 3 (μ3-η1-C⋮ …

Skeletal Isomerization of the [Pt3(μ‐PPh2)3Ph(PPh3)2] Cluster by Recrystallization in Various Solvents

R Bender, P Braunstein, A Tiripicchio… - … Edition in English, 1985 - Wiley Online Library
The solvent used for crystallization determines which of the two structural isomers of [Pt3 (μ‐
PPh2) 3Ph (PPh3) 2] 1 is formed. The isomer 1a is obtained in crystalline form from …