Recent advances in 3d-4f magnetic complexes with several types of non-carboxylate organic ligands

HS Wang, K Zhang, Y Song, ZQ Pan - Inorganica Chimica Acta, 2021 - Elsevier
Since 1993, single molecule magnets (SMMs) have received a wide attention for their
potential applications in high-density information storage device, quantum computer and …

A review of manganese-based molecular magnets and supramolecular architectures from phenolic oximes

CI Yang, ZZ Zhang, SB Lin - Coordination Chemistry Reviews, 2015 - Elsevier
Phenolic oximes, which are frequently used as bridging ligands in the construction of
molecule-based magnets, have stimulated considerable interest in magnetochemistry. This …

Modelling spin Hamiltonian parameters of molecular nanomagnets

T Gupta, G Rajaraman - Chemical Communications, 2016 - pubs.rsc.org
Molecular nanomagnets encompass a wide range of coordination complexes possessing
several potential applications. A formidable challenge in realizing these potential …

[HTML][HTML] The performance and efficiency of twelve range-separated hybrid DFT functionals for calculation of the magnetic exchange coupling constants of di-nuclear …

S Shil, D Bhattacharya - Computational and Theoretical Chemistry, 2024 - Elsevier
The performance and efficiency of twelve range-separated hybrid functionals are compared
with each other in calculating magnetic exchange coupling constant (J) data on eleven di …

Theoretical Studies on Hexanuclear [M33-O/OH)]2 (M = Fe(III), Mn(III), and Ni(II)) Clusters: Magnetic Exchange, Magnetic Anisotropy, and Magneto-Structural …

MK Singh, G Rajaraman - Inorganic chemistry, 2019 - ACS Publications
Controlling spin Hamiltonian parameters such as magnetic exchange and magnetic
anisotropy of polynuclear clusters is of great interest in the area of single molecule magnets …

Semiempirical Magnetostructural Correlation for High-Nuclearity MnIII-Oxo Complexes: Accommodation of Different Relative Jahn–Teller Axis Orientations

KHK Lee, G Christou - Inorganic Chemistry, 2023 - ACS Publications
The previous development of a magnetostructural correlation (MSC) for polynuclear
FeIII/oxo clusters has now been extended to one for polynuclear MnIII/oxo clusters. A …

Modulation of magnetic anisotropy and exchange interaction in phenoxide-bridged dinuclear co (II) complexes

AK Kharwar, A Mondal, A Sarkar… - Inorganic …, 2021 - ACS Publications
We report a new class of four dimeric Co (II) complexes [Co2 (bbpen)(X) 2](H2bbpen= N,
N′-bis (2-hydroxybenzyl)-N, N′-bis (2-methylpyridyl) ethylenediamine)[X–= SCN (1), Cl …

Selective Formation, Reactivity, Redox and Magnetic Properties of MnIII and FeIII Dinuclear Complexes with Shortened Salen-Type Schiff Base Ligands

L Rigamonti, P Zardi, S Carlino, F Demartin… - International Journal of …, 2020 - mdpi.com
The reactivity of the shortened salen-type ligands H3salmp, H2salmen and H2sal (pX) ben
with variable para-substituent on the central aromatic ring (X= t Bu, Me, H, F, Cl, CF3, NO2) …

Understanding the Mechanism of Magnetic Relaxation in Pentanuclear {MnIVMnIII2LnIII2} Single-Molecule Magnets

KR Vignesh, SK Langley, B Moubaraki… - Inorganic …, 2018 - ACS Publications
A new family of heterometallic pentanuclear complexes of formulas [MnIVMnIII2LnIII2O2
(benz) 4 (mdea) 3 (NO3) 2 (MeOH)](Ln= Dy (1-Dy), Tb (2-Tb), Gd (3-Gd), Eu (4-Eu), Sm (5 …

Theoretical Studies on Trinuclear {MnIII2GdIII} and Tetranuclear {MnIII2GdIII2} Clusters: Magnetic Exchange, Mechanism of Magnetic Coupling, Magnetocaloric …

T Rajeshkumar, R Jose, PR Remya… - Inorganic …, 2019 - ACS Publications
Among various applications that are proposed for {3d–4f} clusters, magnetic refrigeration
based on the principle of the magnetocaloric effect (MCE) is gaining attention in recent years …